dichlorobis(4-methylpiperidine-N)(4-methylpyridine-N)nickel(II) | 188925-85-1

• 英文名称: dichlorobis(4-methylpiperidine-N)(4-methylpyridine-N)nickel(II)
• CAS: 188925-85-1
• 化学式: C₁₈H₃₃Cl₂N₃Ni
• 分子量: 421.076
• InChiKey: VKBMUJVFCVVZHJ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  4-甲基哌啶 、 nickel dichloride 以 xylene 为溶剂， 生成 dichlorobis(4-methylpiperidine-N)(4-methylpyridine-N)nickel(II)
  参考文献：
  名称：

  Structural Investigation of Ni^IIComplexes. XI. Dichlorobis(4-methylpiperidine-N)(4-methylpyridine-N)nickel(II)

  摘要：

  Molecules of the title compound, [NiCl2(C6H7N)(C6H13N)(2)], lie on crystallographic twofold axes which pass through each Ni atom and 4-methylpyridine ligand. The coordination polyhedron around the Ni-II centre is distorted trigonal bipyramidal with an N3Cl2 coordination sphere; the equatorial plane is formed by two chloride ions and the N atom of the 4-methylpyridine ligand, while the axial positions are occupied by the N atoms of the 4-methylpiperidine groups.

  DOI：

  10.1107/s010827019601284x