Cp(molybdenum)dinitrosyl(methyl) | 57034-48-7

• 英文名称: Cp(molybdenum)dinitrosyl(methyl)
• 英文别名: (η-C5H5)Mo(NO)2(CH3)
• CAS: 57034-48-7
• 化学式: C₆H₈MoN₂O₂
• 分子量: 236.082
• InChiKey: PAAITCHKVBRVQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  双(环戊二烯)钴 、 Cp(molybdenum)dinitrosyl(methyl) 以 乙醚 为溶剂， 以63%的产率得到{Cp(molybdenum)dinitrosyl(methyl)}{cobalticinium}
  参考文献：
  名称：

  Legzdins, Peter; Wassink, Berend, Organometallics, 1988, vol. 7, # 2, p. 482 - 493

  摘要：

  DOI：
• 作为产物：
  描述：

  (η-C5H5)Mo(NO)2Cl 在 三甲基铝 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 以46%的产率得到Cp(molybdenum)dinitrosyl(methyl)
  参考文献：
  名称：

  Legzdins, Peter; Wassink, Berend, Organometallics, 1988, vol. 7, # 2, p. 482 - 493

  摘要：

  DOI：

文献信息

• Structure and Reactivity of (η-C₅R₅)Mo(NO)₂−Halide, −Halomethyl, and −Alkyl Complexes:  Consecutive Aerobic Methylene and Nitrosyl Ligand Oxidation
  作者：Wendy L. Elcesser、Morten Sörlie、John L. Hubbard

  DOI：10.1021/om960028c

  日期：1996.5.14

  Cp'Mo(NO)(2)(CH(2)X) complexes are isolated in 80-90% yield after the treatment of the Cp'Mo(NO)(2)X complexes in CH2Cl2 with ethereal diazomethane in the presence of Cu powder (Cp' = eta-C5H5 (CP), eta-C-5(CH3)(5)(Cp*); X = Cl, Br). The Cp'Mo(NO)(2)(CH2I) derivatives are obtained in over 90% yield by treating the Cp'Mo(NO)(2)(CH2Cl) derivatives with NaI in THF. Four new halomethyl complexes have been characterized by X-ray crystallography and are compared to the related CpMo(NO)(2)Br, Cp*Mo(NO)(2)Cl, and Cp*Mo(NO)(2)(CH3) derivatives. The structural data and IR data indicate the donor properties of the halomethyl ligands to be intermediate between halide and alkyl ligands. The Cp'Mo(NO)(2)(CH(2)X) complexes react initially with O-2 to give CH2O and the regeneration of the parent Cp'Mo(NO)(2)X complexes. The Cp'Mo(NO)(2)Cl complexes react with O-2 after an induction period to give the well-known Cp'MoO2Cl complexes, NO2, NOCl, and N2O. Exposure of CpCr(NO)(2)(CH(CH3)Br) to O-18(2) gives O-18=CH(CH3) and O-16-labeled CpCr(NO)(2)Br. The Cp'Mo(NO)(2)-alkyl complexes react with O-2 to give the corresponding Cp'MoO2-alkyl derivatives in 40-70% yield (alkyl = CH3, CH2CH3). Electrochemical data show the Mo complexes to oxidize at 0.2-0.3 V lower than the Cr congeners.