| 163227-42-7

• CAS: 163227-42-7
• 化学式: C₄₄H₅₂MnNO₉
• 分子量: 793.836
• InChiKey: SWGBVUGLUNTQLG-YBMFPLBTSA-N

反应信息

• 作为产物：
  描述：

  pentacarbonyl(methyl)manganese(I) 、 [4-[(4-dodecanoyloxyphenyl)iminomethyl]phenyl] 4-octoxybenzoate 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterisation of rod-like metallomesogens of Mn(I) based on Schiff base ligands

  摘要：

  Complexation of liquid-crystalline imines to Mn(I) carbonyls led to liquid-crystalline complexes when the ligated imine was sufficiently anisotropic. Thus, all two-ring and some three-ring imine ligands were not mesomorphic when complexed, while some three-ring and all four-ring imines led to mesomorphic complexes. As expected, complexation disturbed the anisotropy of the ligands and led to a lowering of clearing points and a suppression of smectic phase formation. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00437-3