| 221359-61-1

• CAS: 221359-61-1
• 化学式: C₃₂H₄₁ClIrNO₂
• 分子量: 699.356
• InChiKey: ASHGAPAAFOOGKM-RFCADEKQSA-L

反应信息

• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Hydrocarbon bridged metal complexes, XLIV. Donor–acceptor substituted Schiff bases of polyenes with transition metals2

  摘要：

  Schiff bases 1-10 were obtained by condensation of L-valine and o-aminophenol with donor and ferrocenyl substituted carotinoid aldehydes. From these Schiff bases and chloro-bridged complexes [(R3P)(Cl)M(mu-Cl)](2) (M =Pd, Pt), [(eta(5)-C5Me5) (Cl)Ir(mu-Cl)](2) and [(p-cymene) (Cl)Ru(mu-Cl)](2) a series of mono and heterobimetallic compounds 11-45 was synthesized. The structures of [p-MeO-C6H4-CH=N-C6H4-O-Ru (Cl) (p-cymene)] 16, [ferrocenyl-CH=N-C6H4-O-Ir (Cl) (Cp*)] 23, [(p-Me2NC6H4-CH=CH-C(Me)=CH-CH=CH-CH=C(Me)-CH=N-C6H4-O-Pd(Cl)PEt3] 42 and of the condensation product from [(eta(6)-aniline)Cr(CO)(3)(-)] with 9-ferrocenyl-2,7-dimethylnonatetraene-1-al 46 were determined by X-ray diffraction. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00290-3