[Me2Si(η5-C5H4)2Zr(CH2CCH2B(C6F5)3)] | 922492-83-9

• 英文名称: [Me2Si(η5-C5H4)2Zr(CH2CCH2B(C6F5)3)]
• CAS: 922492-83-9
• 化学式: C₃₄H₁₈BF₁₅SiZr
• 分子量: 841.613
• InChiKey: WFCOPUDYRWWLLV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  ansa-dimethylsilanediyl-dicyclopentadienyl-zirconacyclopent-3-yne 、 三(五氟苯基)硼烷 以 甲苯 为溶剂， 以53%的产率得到[Me2Si(η5-C5H4)2Zr(CH2CCH2B(C6F5)3)]
  参考文献：
  名称：

  Synthesis of ansa-Dimethylsilanediyl−dicyclopentadienyl− zirconacyclopent-3-yne, Me₂Si(η⁵-C₅H₄)₂Zr(η⁴-H₂C₄H₂), and Its Reactions with Ni(0) and B(C₆F₅)₃

  摘要：

  The synthesis and reactions of ansa-dimethylsilanediyl-dicyclopentadienyl-zirconacyclopent-3-yne, Me2Si(eta(5)-C5H4)(2)Zr(eta(4)-H2C4H2) (7), are described. Complexation by Ni(0) complexes gives an external coordination of the triple bond and formation of the complex Me2Si(eta(5)-C5H4)(2)Zr[mu(eta(4)-H2C4H2)]Ni(PPh3)(2) (8), representing a mu-"cis"-complexation of 1,2,3-butatrienes, which is described and compared with the coordination of similar complexes. The reaction of complex 7 with B(C6F5)(3) results in ring opening of the 1-zirconacyclopent-3-yne and formation of the zwitterionic complex [Me2Si(eta(5)-C5H4)(2)Zr](+)-CH2CCCH2-[B-(C6F5)(3)] (9), with the but-2-yne-1,4-diyl ligand bridging the zirconocenium center and the formed boranate. All complexes were characterized by X-ray analysis.

  DOI：

  10.1021/om0608760