[Cu2(salicylate)(salicylic acid -H)][ClO4] | 943764-76-9

• 英文名称: [Cu2(salicylate)(salicylic acid -H)][ClO4]
• 英文别名: [Cu2(salicylate)(salicylic acid-H)][ClO4]
• CAS: 943764-76-9
• 化学式: C₃₄H₂₅Cu₂N₄O₆*ClO₄
• 分子量: 812.138
• InChiKey: HTSPUUZEZPJFBQ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Cu₂(OAc)(OH)(H₂O)(2,2′-bpy)₂](ClO₄) 、 水杨酸 以 甲醇 为溶剂， 以35%的产率得到[Cu2(salicylate)(salicylic acid -H)][ClO4]
  参考文献：
  名称：

  A novel dimeric copper salicylate with an undissociated COOH group: Synthesis and crystal structure of [Cu2(HSal)(Sal)(2,2′-bpy)2](ClO4)

  摘要：

  A dinuclear copper salicylate [Cu-2(HSal)(Sal)(2,2'-bpy)(2)](ClO4) (1) (H(2)Sal = salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies. The molecular structure of 1, determined by single-crystal X-ray diffraction studies, shows the presence of incompletely deprotonated salicylate ligands in the complex. Hydrogen bonding interactions and pi-pi aromatic stacking lead to the formation of 2D polymeric structure in the solid state. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.05.025