[Mo(CO)2(Ph2PCH2PPh2)2(η(5)-C8H11)](1+) | 171558-37-5

• 英文名称: [Mo(CO)2(Ph2PCH2PPh2)2(η(5)-C8H11)](1+)
• CAS: 171558-37-5
• 化学式: C₃₅H₃₃MoO₂P₂
• 分子量: 643.533
• InChiKey: DSELUMZWBXWONW-SWWVHBSRSA-N

反应信息

• 作为反应物：
  描述：

  [Mo(CO)2(Ph2PCH2PPh2)2(η(5)-C8H11)](1+) 在 CO 作用下， 以 二氯甲烷 为溶剂， 生成 [Mo(CO)3(Ph2PCH2PPh2)2(η(3)-2,4-C8H11)](1+)
  参考文献：
  名称：

  Dalton communications. Cyclooctadienyl complexes of molybdenum: synthesis and η⁵→η³hapticity interconversion

  摘要：

  The cyclooctadienylmolybdenum complexes [MoBr(CO)(2)(NCMe)(2)(eta(3)-2.5-C8H11)] and [MoBr(CO)(2)(NCMe)(2)(eta(3)-2.4-C8H11)]. accessible by reaction of [Mo(CO)(2)(NCMe)(3)] with bromocyclooctadienes. have been found to be precursors to the pentahapto-bonded complexes [Mo(CO)(2)(L-L)(eta(2),eta(3)-2,5-C8H11)](+) [L-L=Ph(2)PCH(2)PPh(2) (dppm) (crystallographically characterised) or Ph(2)PCH(2)CH(2)PPh(2)] and [Mo(CO)(2)(dppm)(eta(5)-C8H11)](+); the reactivity of the last three complexes towards eta(5)-->eta(3) hapticity conversion at the dienyl ligand is controlled by the bonding mode of the cyclooctadienyl ligand and the identity of L-L.

  DOI：

  10.1039/dt9950002915
• 作为产物：
  描述：

  silver tetrafluoroborate 、 [MoBr(CO)2(Ph2PCH2PPh2)2(η(3)-2,4-C8H11)] 以 二氯甲烷 为溶剂， 以79%的产率得到[Mo(CO)2(Ph2PCH2PPh2)2(η(5)-C8H11)](1+)
  参考文献：
  名称：

  Dalton communications. Cyclooctadienyl complexes of molybdenum: synthesis and η⁵→η³hapticity interconversion

  摘要：

  The cyclooctadienylmolybdenum complexes [MoBr(CO)(2)(NCMe)(2)(eta(3)-2.5-C8H11)] and [MoBr(CO)(2)(NCMe)(2)(eta(3)-2.4-C8H11)]. accessible by reaction of [Mo(CO)(2)(NCMe)(3)] with bromocyclooctadienes. have been found to be precursors to the pentahapto-bonded complexes [Mo(CO)(2)(L-L)(eta(2),eta(3)-2,5-C8H11)](+) [L-L=Ph(2)PCH(2)PPh(2) (dppm) (crystallographically characterised) or Ph(2)PCH(2)CH(2)PPh(2)] and [Mo(CO)(2)(dppm)(eta(5)-C8H11)](+); the reactivity of the last three complexes towards eta(5)-->eta(3) hapticity conversion at the dienyl ligand is controlled by the bonding mode of the cyclooctadienyl ligand and the identity of L-L.

  DOI：

  10.1039/dt9950002915