[Ru(η(6)-C6Me6)Cl2(2,4,6-Me3C6H2NC)] | 162889-95-4

• 英文名称: [Ru(η(6)-C6Me6)Cl2(2,4,6-Me3C6H2NC)]
• CAS: 162889-95-4
• 化学式: C₂₂H₂₉Cl₂NRu
• 分子量: 479.455
• InChiKey: XQFGDDIESLQNFP-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [Ru(η(6)-C6Me6)Cl2(2,4,6-Me3C6H2NC)] 、 苯乙炔 在 KOH 作用下， 以 甲醇 为溶剂， 以34%的产率得到[Ru(η(6)-C6Me6)Cl(C.tplbond.CPh)(2,4,6-Me3C6H2NC)] * 0.25 CH2Cl2
  参考文献：
  名称：

  Preparation of [Ru(η⁶-C₆Me₆)Cl(CCPh)(RNC)](R = C₈H₉or C₆H₂Me₃-2,4,6) and its reaction with tetracyanoethylene. Crystal structures of [Ru(η⁶-C₆Me₆)Cl{C[C(CN)₂]CPhC(CN)₂}(C₈H₉NC)] and cis-[RuCl₂(C₈H₉NC)₂]

  摘要：

  Reaction of [Ru(eta(6)-C(6)Me(6))Cl-2(RNC)] with phenylacetylene in the presence of potassium hydroxide in methanol gave the corresponding acetylide complex [Ru(eta(6)-C(6)Me(6))Cl(C=CPh)(RNC)] (R = C8H9 1a or 2,4,6-Me(3)C(6)H(2) 1b). Compound la reacted with triphenylphosphine at reflux in toluene to give [RU(eta(6)-C(6)Me(6))Cl(C=CPh)(PPh(3))] 2 and [RUCl(C=CPh)(C8H9NC)(PPh(3))] 3. When 1a was treated with tetracyanoethylene (tcne) at room temperature [Ru(eta(6)-C(6)Me(6))Cl{C[=C(CN)(2)]CPh=C(CN)(2)}(C8H9NC)] 4 was obtained. The structure was confirmed by an X-ray analysis: space group Pbca, a = 20.128(4), b = 17.821(6), c = 17.407(9) Angstrom, and Z = 8. The molecule contains a ligand resulting from alpha,beta addition. of C(CN)(2) fragments to the acetylide group. Reaction of 2 with tcne gave [RU(eta(6)-C(6)Me(6))Cl{C(CN)(2)CPhC=C(CN)(2)}] 5 which has lost the terminal isocyanide in 4. Preparation and X-ray analysis of square-planar cis-[RuCl2(C8H9NC)(2)] were also carried out: space group P ($) over bar 1, a = 10.573(3), b = 10.865(3), c = 8.244(2) Angstrom, alpha = 99.66(2), beta = 93.37(2). gamma = 85.85(3)degrees and Z = 2. The structure consists of a pair of molcules of cis configuration with a centrosymmetry, but there is no interaction between the ruthenium atoms.

  DOI：

  10.1039/dt9950000307