tris(pentafluorothiophenolato)tris(2,6-dimethylphenylisocyanide)chromium(III) | 191798-42-2

• 英文名称: tris(pentafluorothiophenolato)tris(2,6-dimethylphenylisocyanide)chromium(III)
• CAS: 191798-42-2
• 化学式: C₄₅H₂₇CrF₁₅N₃S₃
• 分子量: 1042.9
• InChiKey: JWORNOIKCUPMJN-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  、 2,6-二甲基苯基异腈 以 甲苯 为溶剂， 以35%的产率得到tris(pentafluorothiophenolato)tris(2,6-dimethylphenylisocyanide)chromium(III)
  参考文献：
  名称：

  Interaction of xylylisocyanide with CrVI(Nmesityl)2(SC6F5)2

  摘要：

  The interaction of 2,6-dimethylphenylisocyanide (xylNC) with Cr(Nmes)(2)(SC6F5)(2) in refluxing toluene gives mer-Cr(SC6F5)(3)(xylNC)(3) 1 and minor amounts of trans-Cr(SC6F5)(2)(xylNC)(4) 2. Compound 2 is best made by interaction of either Cr(mes)(2)(THF)(3) or CrCl2 with C6F5SH or C6F5SNa, respectively, in the presence of xylNC. The X-ray crystal structures of 1 and 2 have been determined. The similar imido thiolates of molybdenum(VI) are inert towards xylNC. (C) 1997 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00600-6