Mo2(O)(μ-O)(μ-C4Ph4)(η-C5H5)2 | 212250-49-2

• 英文名称: Mo2(O)(μ-O)(μ-C4Ph4)(η-C5H5)2
• CAS: 212250-49-2
• 化学式: C₃₈H₃₀Mo₂O₂
• 分子量: 710.535
• InChiKey: IPOSYUMZEGLAEK-RKMMQJJESA-N

反应信息

• 作为反应物：
  描述：

  dicobalt octacarbonyl 、 Mo2(O)(μ-O)(μ-C4Ph4)(η-C5H5)2 以 甲苯 为溶剂， 以29%的产率得到CoMo(CO)4(μ-C4Ph4)(η-C5H5)
  参考文献：
  名称：

  Oxo ligands as assembling units in mixed-metal cluster chemistry: synthesis and X-ray structure of the bow-tie cluster [Mo2Ru3(μ-O)2(μ3-CPh)(μ-C3Ph3)(CO)8(η-C5H5)2]

  摘要：

  The thermal reaction of [Mo-2(O)(mu-O)(mu-C4Ph4)(eta-C5H5)(2)] with [Ru-3(CO)(12)] gives the pentanuclear cluster [Mo2Ru3(mu(3)-O)(2)(mu(3)-CPh)(mu-C3Ph3)(CO)(8)(eta-C5H5)(2)], which has been crystallographically characterised. The compound displays several unusual features: (i) a highly distorted bow-tie structure in which the two metal triangles are virtually perpendicular; (ii) the cleavage of the initial four carbon chain into a dimetalla-allyl fragment and an alkylidyne group; (iii) the presence of two triply-bridging oxo ligands; and (iv) the coordination of one of the phenyl groups of the C3Ph3 ligand to ruthenium.

  DOI：

  10.1016/s0022-328x(96)06834-9
• 作为产物：
  描述：

  Mo2(CO)(μ-C4Ph4)(η-C5H5)2 在 air 作用下， 以 二氯甲烷 为溶剂， 生成 Mo2(O)(μ-O)(μ-C4Ph4)(η-C5H5)2
  参考文献：
  名称：

  Knox, Selby A. R.; Stansfield, Robert F. D.; Stone, F. Gordon A., Journal of the Chemical Society, Dalton Transactions, 1982, p. 173 - 186

  摘要：

  DOI：