μ-oxo-bis(2,3,7,8,12,13,17,18-octaethyl-5,15-dinitroporphyrinato)iron(III) | 172374-75-3

• 英文名称: μ-oxo-bis(2,3,7,8,12,13,17,18-octaethyl-5,15-dinitroporphyrinato)iron(III)
• CAS: 172374-75-3
• 化学式: C₇₂H₈₄Fe₂N₁₂O₉
• 分子量: 1373.23
• InChiKey: PFSZEMRCLNNZRO-GHORTKQASA-N

反应信息

• 作为产物：
  描述：

  iron(III)octaethylporphyrin chloride 、 二氧化氮 以 二氯甲烷 为溶剂， 生成 μ-oxo-bis(2,3,7,8,12,13,17,18-octaethyl-5,15-dinitroporphyrinato)iron(III)
  参考文献：
  名称：

  A μ-Oxo-bis[iron(III) porphyrin] Complex

  摘要：

  Partial nitration of iron(III) 2,3,7,8,12,13,17,18-octaethylporphyrin chloride [Fe-III(OEP)Cl] gives the mu-oxo-bis(5,15-dinitro) compound mu-oxo-bis[2,3,7,8,12,13,17, 18-octaethyl-5,15-dinitroporphyrinato)iron(III)], [Fe-2(C(36)H(4)2N(6)O(4))(2)O], which is similar to other mu-oxo-iron(III) porphyrin complexes but with less ruffling of the porphyrin structure. The porphyrin planes are not parallel [the angle between plane normals is 169 (2)degrees] and the Fe-O-Fe angle is 167.9 (3)degrees. As expected, the Fe atoms are significantly displaced from the porphyrin planes towards the bridging O atom: 0.46 Angstrom for Fe1 and 0.49 Angstrom for Fe2. The two porphyrin residues are eclipsed with respect to their C atoms, but the nitro groups are staggered by 90 degrees from one residue to the other.

  DOI：

  10.1107/s0108270195005701