5,10,15,20-tetrakis(benzo-9-crown-3)porphyrinatoiron(III)chloride | 866917-07-9

• 英文名称: 5,10,15,20-tetrakis(benzo-9-crown-3)porphyrinatoiron(III)chloride
• CAS: 866917-07-9
• 化学式: C₆₀H₅₂ClFeN₄O₁₂
• 分子量: 1112.39
• InChiKey: GVEMCLZCGHONBQ-QZGJPTLTSA-M

反应信息

• 作为反应物：
  描述：

  aluminum(III) nitrate nonahydrate 、 5,10,15,20-tetrakis(benzo-9-crown-3)porphyrinatoiron(III)chloride 以 甲醇 、 氯仿 为溶剂， 生成 [(5,10,15,20-tetrakis(Al-benzo-9-crown-3)porphyrinatoiron(III) chloride(12+)
  参考文献：
  名称：

  Crown ether-appended porphyrins and metalloporphyrins: Synthesis, characterization and metal ions interaction

  摘要：

  Tetrakis(3,4-dimethoxyphenyl)porphyrin (TDMPPH2), tetrakis(benzo-9-crown-3)porphyrin (TC3PH(2)), and tetrakis(benzo-12-crown-4)porphyrin (TC4PH(2)), have been synthesized and characterized by UV-Vis, H-1 NMR, C-13 NMR and IR spectroscopies. These porphyrin derivatives were metallated by Zn2+ and Fe3+ ions. The interactions of Na+, K+, NH4+, Mg2+, Ca2+, Ba2+ and Al3+ cations with TC3PH(2), TC4PH(2), ZnTC3P, FeTC3PCl and (FeTC3P)(2)O were studied. UV-Vis and Al-27 NMR investigations have shown that Al3+ and Mg2+ cations interact with both porphyrin macrocycles and crown ether rings. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.04.033