bis-1,3-dihydrotriphosphane | 890053-60-8

• 英文名称: bis-1,3-dihydrotriphosphane
• CAS: 890053-60-8
• 化学式: C₁₁₈H₂₄₈FeP₆Si₂₄
• 分子量: 2583.01
• InChiKey: TYUFWZFCCHWLCV-JTTVMLOJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis-1,3-dihydrotriphosphane 以 not given 为溶剂， 生成 1,1'-bis(2,4,6-tris[bis(trimethylsilyl)methyl]phenyldiphosphenyl)ferrocene
  参考文献：
  名称：

  Synthesis of 1,1‘-Ferrocenylene-Bridged Bisdiphosphenes

  摘要：

  A simple synthetic access to the first ferrocenylene-bridged bisdiphosphenes Fe(C5H4-P=P-R)(2) is reported. The unsaturated P=P units require steric protection by adjacent substituents such as Dmp (2.6-dimesitylphenyl) and Tbt (2.4,6-tris[bis(trimethylsilyl)methyl]phenyl) and should be capable of conjugative interaction with the central metallocene unit. The electronic situation in these molecules has been assessed on the basis of DFT calculations. As a derivative of the Tbt-substituted bisdiphosphene with Tbt-PH2, the resulting ferrocenylene-bridged bis-1,3-dihydrotriphosphane has been characterized by X-ray crystallography.

  DOI：

  10.1021/om060073c
• 作为产物：
  描述：

  2,4,6-tris[bis(trimethylsilyl)methyl]phenylphosphine 、 1,1'-bis(2,4,6-tris[bis(trimethylsilyl)methyl]phenyldiphosphenyl)ferrocene 以 苯 为溶剂， 以45%的产率得到bis-1,3-dihydrotriphosphane
  参考文献：
  名称：

  Synthesis of 1,1‘-Ferrocenylene-Bridged Bisdiphosphenes

  摘要：

  A simple synthetic access to the first ferrocenylene-bridged bisdiphosphenes Fe(C5H4-P=P-R)(2) is reported. The unsaturated P=P units require steric protection by adjacent substituents such as Dmp (2.6-dimesitylphenyl) and Tbt (2.4,6-tris[bis(trimethylsilyl)methyl]phenyl) and should be capable of conjugative interaction with the central metallocene unit. The electronic situation in these molecules has been assessed on the basis of DFT calculations. As a derivative of the Tbt-substituted bisdiphosphene with Tbt-PH2, the resulting ferrocenylene-bridged bis-1,3-dihydrotriphosphane has been characterized by X-ray crystallography.

  DOI：

  10.1021/om060073c