(4-fluorobenzyl)2SnCl(dithiomorpholincarbamate) | 693781-16-7

• 英文名称: (4-fluorobenzyl)2SnCl(dithiomorpholincarbamate)
• CAS: 693781-16-7
• 化学式: C₁₉H₂₀ClF₂NOS₂Sn
• 分子量: 534.666
• InChiKey: NVGWHVRADLDYPB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium N-morpholinocarbamodithioate 、 di(p-fluorobenzyl)tin(IV) chloride 以 二氯甲烷 为溶剂， 以75%的产率得到(4-fluorobenzyl)2SnCl(dithiomorpholincarbamate)
  参考文献：
  名称：

  Synthesis, spectroscopic properties and crystal structures of SnBr2[S2CN(CH2CH2)2O]2, (4-F-C6H4CH2)2Sn(Cl)S2CN(CH2CH2)2O and (2-F-C6H4CH2)3SnS2CN(CH2CH2)2O

  摘要：

  Three organotin(IV) complexes with dithiomorpholincarbamate ligand: SnBr2[S2CN(CH2CH2)(2)O](2) (1), (4-F-C6H4CH2)(2)Sn(Cl) S2CN(CH2CH2)(2)O (2) and (2-F-C6H4CH2)(3)SnS2CN(CH2CH2)(2)O (3) have been synthesized and characterized by elemental analysis, IR. UV and NMR. Their crystal and molecular structures have been determined by X-ray single crystal diffraction. In the complex 1. the tin atom is rendered six-coordination in a distorted octahedron configuration. And in the complexes 2 and 3, the tin atoms are rendered five-coordination in a distorted trigonal bipyramidal structure. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.01.023