di(tert-butyl)aluminium chloride t-butylhydrazine adduct | 317331-29-6

• 英文名称: di(tert-butyl)aluminium chloride t-butylhydrazine adduct
• CAS: 317331-29-6
• 化学式: C₁₂H₃₀AlClN₂
• 分子量: 264.818
• InChiKey: IOLNZQLMGJNSQU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  di(tert-butyl)aluminium chloride t-butylhydrazine adduct 在 n-BuLi 作用下， 以 正己烷 为溶剂， 以22%的产率得到bis[di(tert-butyl)aluminium-tert-butylhydrazide]
  参考文献：
  名称：

  酰肼铝。与四元 Al2N2 杂环形成二聚二（叔丁基）铝酰肼以及二烷基氯化铝与双（三甲基甲硅烷基）酰肼二锂反应

  摘要：

  The reaction of di(tert-butyl)aluminium chloride with tert-butylhydrazine yielded an adduct (1) which was isolated in a pure form and characterized by crystal structure determination. 1 reacted with n-butyllithium by deprotonation and salt elimination to give the corresponding di(tert-butyl)aluminium hydrazide (2), which is a dimer in solution and in the solid state and possesses a four-membered Al2N2 heterocycle with two exocyclic N-N bonds. The structure of 2 differs from that of other di(tert-butyl)aluminium hydrazides which have four- or five-membered heterocycles. Treatment of impure samples of 1 with n-butyllithium yielded by the cleavage of the N-N bonds a mixture of several un-known products, from which the dimeric, centrosymmetric aluminium amide [(Me3C)(2)AlN(H)CMe3](2) (3) was isolated. A similar product (4) was obtained in a low yield by the reaction of (Me3SiCH2)(2)AlCl with the dilithium hydrazide Li2N2(SiMe3)(2). An intact N-N bond was neither found in the second product isolated from this reaction. Instead a tricyclic compound was formed by C-H activation which has two five-membered AlNSiC2 heterocycles bridged by Al-N bonds.

  DOI：

  10.1002/1521-3749(200011)626:11<2284::aid-zaac2284>3.0.co;2-b
• 作为产物：
  描述：

  叔丁基肼 、 di(tert-butyl)aluminium chloride 以 甲苯 为溶剂， 以76%的产率得到di(tert-butyl)aluminium chloride t-butylhydrazine adduct
  参考文献：
  名称：

  酰肼铝。与四元 Al2N2 杂环形成二聚二（叔丁基）铝酰肼以及二烷基氯化铝与双（三甲基甲硅烷基）酰肼二锂反应

  摘要：

  The reaction of di(tert-butyl)aluminium chloride with tert-butylhydrazine yielded an adduct (1) which was isolated in a pure form and characterized by crystal structure determination. 1 reacted with n-butyllithium by deprotonation and salt elimination to give the corresponding di(tert-butyl)aluminium hydrazide (2), which is a dimer in solution and in the solid state and possesses a four-membered Al2N2 heterocycle with two exocyclic N-N bonds. The structure of 2 differs from that of other di(tert-butyl)aluminium hydrazides which have four- or five-membered heterocycles. Treatment of impure samples of 1 with n-butyllithium yielded by the cleavage of the N-N bonds a mixture of several un-known products, from which the dimeric, centrosymmetric aluminium amide [(Me3C)(2)AlN(H)CMe3](2) (3) was isolated. A similar product (4) was obtained in a low yield by the reaction of (Me3SiCH2)(2)AlCl with the dilithium hydrazide Li2N2(SiMe3)(2). An intact N-N bond was neither found in the second product isolated from this reaction. Instead a tricyclic compound was formed by C-H activation which has two five-membered AlNSiC2 heterocycles bridged by Al-N bonds.

  DOI：

  10.1002/1521-3749(200011)626:11<2284::aid-zaac2284>3.0.co;2-b