Pd3(μ-chloroacetate)6 | 1332888-79-5

• 英文名称: Pd3(μ-chloroacetate)6
• CAS: 1332888-79-5
• 化学式: C₁₂H₁₂Cl₆O₁₂Pd₃
• 分子量: 880.198
• InChiKey: CKZSKCHGWCCVIU-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六(乙酸)三钯(II) 、 氯乙酸 以 苯 为溶剂， 以53%的产率得到Pd3(μ-chloroacetate)6
  参考文献：
  名称：

  Binary palladium carboxylates with electron-donating and electron-withdrawing substituents in the carboxylate ligand: Synthesis and structural studies. The crystal structures of Pd3(μ-CH2ClCO2)6 · CH2Cl2, Pd3(μ-C6H11CO2)6, and Pd3(μ-CMe3CO2)6

  摘要：

  Replacement of the acetate ligands in Pd-3(mu-MeCO2)(6) in benzene gave complexes of the general formula Pd-3(mu-RCO2)(6) (R = CF3, CCl3, CH2Cl, Me, cyclo-C6H11, and CMe3). The structures of the complexes were determined using IR spectroscopy, ESI mass spectrometry, and X-ray diffraction. It was found that the complexes contain a trinuclear Pd framework and that their spectroscopic and structural parameters depend on the donor-acceptor properties of the substituent in the carboxylate ligand.

  DOI：

  10.1134/s1070328411080021