[Et4N][(hydrotris(pyrazol-1-yl)borate)Mo(CO)2(η2-Se2)] | 825626-67-3

• 英文名称: [Et4N][(hydrotris(pyrazol-1-yl)borate)Mo(CO)2(η2-Se2)]
• CAS: 825626-67-3
• 化学式: C₈H₂₀N*C₁₁H₁₀BMoN₆O₂Se₂
• 分子量: 653.164
• InChiKey: RRQIAOGFMREYCA-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [Et4N][(hydrotris(pyrazol-1-yl)borate)Mo(CO)2(η2-Se2)] 在 CF₃SO₃CH₃ 作用下， 以 乙腈 为溶剂， 以74%的产率得到{(hydrotripyrazolylborato)Mo(CO)2}2Se
  参考文献：
  名称：

  Synthesis and X-ray structure of the new Mo diselenido complex with hydrotris(pyrazolyl)borate coligand [Et4N][TpMo(CO)2(η2-Se2)]

  摘要：

  Reaction of the Mo(0) complex [Et(4)N][TpMo(CO)(3)] (Tp = hydrotris(pyrazol-1-yl)borate) with red Se in MeCN at 50 degreesC afforded the Mo(II) cliseleniclo complex [Et(4)N][TpMo(CO)(2)(eta(2)-Se(2))] (2), whose structure has been determined in detail by the single-crystal X-ray diffraction. By treatment with MeOSO(2)CF(3) in MeCN, 2 was converted into the selenido-bridged dimolybdenum complex [{TpMo(CO)(2)}(2)(mu-Se)] with concomitant formation of MeSeSeMe. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.06.035
• 作为产物：
  描述：

  selenium 、 tetraethylammonium tricarbonylmolybdenum(0) hydridotris(1-pyrazolyl)borate 以 乙腈 为溶剂， 以60%的产率得到[Et4N][(hydrotris(pyrazol-1-yl)borate)Mo(CO)2(η2-Se2)]
  参考文献：
  名称：

  Synthesis and X-ray structure of the new Mo diselenido complex with hydrotris(pyrazolyl)borate coligand [Et4N][TpMo(CO)2(η2-Se2)]

  摘要：

  Reaction of the Mo(0) complex [Et(4)N][TpMo(CO)(3)] (Tp = hydrotris(pyrazol-1-yl)borate) with red Se in MeCN at 50 degreesC afforded the Mo(II) cliseleniclo complex [Et(4)N][TpMo(CO)(2)(eta(2)-Se(2))] (2), whose structure has been determined in detail by the single-crystal X-ray diffraction. By treatment with MeOSO(2)CF(3) in MeCN, 2 was converted into the selenido-bridged dimolybdenum complex [{TpMo(CO)(2)}(2)(mu-Se)] with concomitant formation of MeSeSeMe. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.06.035