tetramethylammonium trichloromercurate | 4473-11-4

• 英文名称: tetramethylammonium trichloromercurate
• 英文别名: Me4N[HgCl3]
• CAS: 4473-11-4
• 化学式: C₄H₁₂N*Cl₃Hg
• 分子量: 381.095
• InChiKey: YBNGSFSIJYQFFS-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.39
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  (CH₃)4N⁽¹⁺⁾*Hg₆Cl₁₃^(1-)=(CH₃)4N{Hg₆Cl₁₃} 在 ether 作用下， 生成 tetramethylammonium trichloromercurate
  参考文献：
  名称：

  Stroemholm, D., Journal fur praktische Chemie (Leipzig. 1834), 1902, vol. 66, p. 423 - 474

  摘要：

  DOI：

文献信息

• Far-infrared and Raman spectra of crystalline tetra-alkylammonium trihalogenomercurate(II) salts. Evidence for monomeric or halogen-bridged associated anions depending on the cation
  作者：Roger M. Barr、Michael Goldstein

  DOI：10.1039/dt9760001593

  日期：——

  made of the far-infrared (20–400 cm–1) and Raman spectra of eight compounds of type [NR4][HgX3](R = Me, Et, Prn, or Bun; X = Cl, Br, or I) and of [SMe3][HgI3] in the solid state. Solution-phase Raman data have also been obtained. For R = Et and X = Cl two crystalline modifications have been identified. The low-temperature α form has vibrational spectra explicable in terms of an essentially monomeric

  已经对八种[NR 4 ] [HgX 3 ]类型的化合物的远红外光谱（20–400 cm –1）和拉曼光谱进行了研究（R = Me，Et，Pr n或Bu n； X = Cl，Br或I）和[SMe 3 ] [HgI 3 ]的固态。还获得了溶液相拉曼数据。对于R ＝ Et和X ＝ Cl，已经鉴定了两个晶体修饰。低温α形式的振动光谱可以解释为基本上是单体的阴离子结构，而β形式在71°C以上稳定，显然含有强的卤化物桥基。通过与α-和β-[NEt 4 ] [HgCl3 ]。因此，相关的阴离子结构也存在于[NEt 4 ] [HgX 3 ]（X = Br或I），[NPr n 4 ] [HgCl 3 ]和[NBu n 4 ] [HgI 3 ]中。显然，在定性解释振动数据时，可以忽略在[SMe 3 ] [HgI 3 ]和[NMe 4 ] [HgCl 3 ]的晶体结构中发现的弱卤素桥。[NMe 4 ] [HgX
• Synthesis of Mercury(II) and Palladium(II) Organometallic Derivatives of Terephthaldehyde by Metalation, Transmetalation, Oxidation, and Condensation Reactions. X-ray Crystal Structures of <i>trans</i>-[PdCl{C₆H₃(CO₂H)₂-2,5}(PPh₃)₂]·Me₂CO·2MeOH, <i>trans</i>-[PdCl{C₆H₃(CHO)-2-(CO₂H)-5}(PPh₃)₂]·2CH₂Cl₂, and [Pd{C₆H₃(CHNC₆H₄NH₂-4)-2-(CHO)-5}(<i>N</i>,<i>N</i>,<i>N</i>‘,<i>N</i>‘-Tetramethylethylenediamine)]CF₃SO₃. Molecular Assemblies through [Pd]−Cl···HO₂C−Aryl and [Pd]−Cl···HOMe  HO(O)C−Aryl Hydrogen Bonds
  作者：José Vicente、José-Antonio Abad、Barbara Rink、Francisco-Santos Hernández、M. Carmen Ramírez de Arellano

  DOI：10.1021/om970583u

  日期：1997.11.1

  5}] (1) and [HgC6H3(CHO)2-2,5}2] (2) have been prepared by mercuriation of terephthaldehyde. Palladium complexes [PdClC6H3(CHO)2-2,5}(N-N)] (N-N = N,N,N‘,N‘-tetramethylethylenediamine (tmeda) (3) or 2,2‘-bipyridine (bpy) (3‘)) or trans-[PdClC6H3(CHO)2-2,5}(PPh3)2]·H2O (4) have been obtained by reacting (Me4N)2[Pd2Cl6] or trans-[PdCl2(PPh3)2], respectively, with 1 or 2. The reaction of potassium permanganate

  有机汞[HgCl C 6 H 3（CHO）2 -2,5}]（1）和[Hg C 6 H 3（CHO）2 -2,5} 2 ]（2）已通过汞化制备。对苯二甲醛。钯配合物[PdCl C 6 H 3（CHO）2 -2,5}（NN）]（NN = N，N，N '，N'-四甲基乙二胺（TMeDA）（3）或2,2'-联吡啶（ bpy）（3 '））或反式-[PdCl C 6 H 3（CHO）通过使（Me 4 N）2 [Pd 2 Cl 6 ]或反式-[PdCl 2（PPh 3）2 ]分别获得2 -2,5}（PPh 3）2 ]·H 2 O（4），带有1或2。高锰酸钾与配合物3和3 '或汞1的反应导致5-甲酰基取代基的选择性氧化，从而提供[PdCl C 6 H 3（CHO）-2-（CO 21H）-5}（NN）]（NN = TMEDA（5），联吡啶（5 “））或分别的混合物的主要成分是完全氧化的[的HgClÇ
• Structural, vibrational and electrical studies of tetramethylammonium trichloromercurate [(CH3)4N]HgCl3
  作者：F. Lambarki、A. Ouasri、A. Rhandour、M. Saadi、L. El Ammari、L. Hajji

  DOI：10.1016/j.molstruc.2018.07.051

  日期：2018.12

  crystal structure of [(CH3)4N]HgCl3 is redetermined at 298 K in monoclinic system [P21(Z = 4); a = 7.5501(3) A, b = 15.6871(6) A, c = 8.8666(4) A, β = 93.575(2)°]. The anionic sublattice of the crystal is consisted of (HgCl3−)n polyhedra sharing a vertex to form zigzag chains along the a-axis. The crystal structure cohesion is ensured by C -H⋯Cl hydrogen bonds that connect organic (CH3)4N+ and mineral

  摘要 [(CH3)4N]HgCl3 的晶体结构在 298 K 时在单斜晶系 [P21(Z = 4); a = 7.5501(3) A, b = 15.6871(6) A, c = 8.8666(4) A, β = 93.575(2)°]。晶体的阴离子亚晶格由共享一个顶点的 (HgCl3-)n 多面体组成，沿 a 轴形成锯齿形链。晶体结构内聚力由连接有机 ( )4N+ 和矿物部分的 C -H⋯Cl 氢键确保。在室温下研究的红外 (450-4000 cm-1) 和拉曼 (50-3500 cm-1) 光谱证实了有机阳离子 ( )4N+ 和 (HgCl3-)n 聚合物通过 CH⋯Cl 氢键连接。通过 DSC (269°/260 °C) 和介电测量 (254 °C) 观察并研究了该化合物的一个相变。介电常数随温度的变化表明观察到的转变是铁顺电类型的。已执行阻抗复数的 Cole-Cole 图。从直流电导率分析获得的活化能
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Hg: MVol.B1, 15, page 355 - 371
  作者：

  DOI：——

  日期：——
• Orthomercurated and cycloaurated derivatives of the iminophosphorane Ph3PNPh
  作者：Samuel D.J. Brown、William Henderson、Kelly J. Kilpin、Brian K. Nicholson

  DOI：10.1016/j.ica.2006.02.009

  日期：2007.3

  Ortho-lithiation of Ph-3=NPh followed by reaction with HgCl2 gave good yields of [HgC6H4(PPh2=NPh)-2}Cl], 3, which was characterised spectroscopically and by an X-ray crystal structure determination. This is an isomer of the product of direct mercuration of Ph3P=NPh which occurs on the N-bonded phenyl ring [J. Vicente, J.A. Abad, R. Clemente, J. Lopez-Serrano, M.C. Ramirez de Arellano, P.G. Jones, D. Bautista, Organometallics, 22 (2003) 4248]. Transmetallation of 3 with [AuCl4](-) gave the corresponding cycloaurated complex [Aukappa(2)-C,N-C6H4(PPh2=NPh)-2}Cl-2] with a five-membered metallocyclic ring incorporating four different elements. (c) 2006 Elsevier B.V. All rights reserved.