Pd3(2,6-dimethylphenyl isocyanide)6 | 89668-96-2

• 英文名称: Pd3(2,6-dimethylphenyl isocyanide)6
• 英文别名: [Pd3(CNC6H3-2,6-Me2)6]；Pd3(2,6-Me2C6H3NC)6；[Pd(2,6-dimethylisocyanide)2]3
• CAS: 89668-96-2
• 化学式: C₅₄H₅₄N₆Pd₃
• 分子量: 1106.32
• InChiKey: JZMJZBKIYFPQSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Pd3(2,6-dimethylphenyl isocyanide)6 、 溴代三氟代乙烯 以 乙醚 为溶剂， 以68%的产率得到trans-[Pd(CNC6H3-2,6-Me2)2Br(CFCF2)]
  参考文献：
  名称：

  二甲苯基异氰化物铂和钯配合物

  摘要：

  双（环辛基-1,5-二烯）铂与异丙基异氰化物反应生成三核络合物[Pt 3（CNPr i）6 ]。通过用2，6-二甲基苯基异氰酸酯处理[Pd（dba）2 ]或[Pd 2（dba）2 CHCl 3 ]来制备相关的钯化合物。簇[Pt 3（CNC 6 H 3 -2,6-Me 2）6 ]及其推测的钯类似物与烯烃（NC）2 C：C（CN）2，F 2 C：CFCl和（CN）的反应）2 C：C（CF 3）2，得到化合物[M（烯烃）（CNC 6 ħ 3 -2,6-ME 2）2 ]（M铂，钯），其中的金属是η 2键合的，以协调烯烃。化合物[Pd 3（CNC 6 H 3 -2,6-Me 2）6 ]与F 2 C：CFBr和F 2 C：CFCl反应，得到反式配合物[Pd（X）（C 2 F 3） （CNC 6 H 3 -2,6-Me 2）2 ]（XBr，Cl）。相似化合物[M（L）-（CNC 6 H 3-2,6-Me

  DOI：

  10.1016/0022-328x(83)87186-1
• 作为产物：
  描述：

  2,6-二甲基苯基异腈 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 以 正己烷 为溶剂， 以75-91的产率得到Pd3(2,6-dimethylphenyl isocyanide)6
  参考文献：
  名称：

  二甲苯基异氰化物铂和钯配合物

  摘要：

  双（环辛基-1,5-二烯）铂与异丙基异氰化物反应生成三核络合物[Pt 3（CNPr i）6 ]。通过用2，6-二甲基苯基异氰酸酯处理[Pd（dba）2 ]或[Pd 2（dba）2 CHCl 3 ]来制备相关的钯化合物。簇[Pt 3（CNC 6 H 3 -2,6-Me 2）6 ]及其推测的钯类似物与烯烃（NC）2 C：C（CN）2，F 2 C：CFCl和（CN）的反应）2 C：C（CF 3）2，得到化合物[M（烯烃）（CNC 6 ħ 3 -2,6-ME 2）2 ]（M铂，钯），其中的金属是η 2键合的，以协调烯烃。化合物[Pd 3（CNC 6 H 3 -2,6-Me 2）6 ]与F 2 C：CFBr和F 2 C：CFCl反应，得到反式配合物[Pd（X）（C 2 F 3） （CNC 6 H 3 -2,6-Me 2）2 ]（XBr，Cl）。相似化合物[M（L）-（CNC 6 H 3-2,6-Me

  DOI：

  10.1016/0022-328x(83)87186-1

文献信息

• A-frame trinuclear complexes of platinum and palladium with a tridentate phosphine ligand insertion of d10 Pt(0) and Pd(0) fragments into a Pt-Pt σ-bond
  作者：Tomoaki Tanase、Hiroyuki Takahata、Hirokazu Ukaji、Masaru Hasegawa、Yasuhiro Yamamoto

  DOI：10.1016/s0022-328x(96)06714-9

  日期：1997.6

  (dpmp = bis(diphenylphosphinomethyl)phenylphosphine) with [M3(RNC)6] (M = Pt, Pd) afforded trimetallic A-frame clusters, [Pt2M(μ-dpmp)2(RNC)2](PF6)2 (6: M = Pt, R = xylyl (Xyl); 7: M = Pd, R = mesityl (Mes)). The d10 Pt0(RNC)2 and Pd0(RNC)2 fragments were shown to be inserted into the Pt-Pt σ-bond of complex 3 by spectroscopic and X-ray crystallographic analyses. The uncoordinated phosphine units in

  的反应的抗[铂- 2（μ -dPMP）2（RNC）2 ]（PF 6）2（3用[M）（DPMP =双（二苯基膦基）苯基）3（RNC）6 ]（M =铂，钯）提供三金属A框架簇，[Pt 2 M（μ- dPMP）2（RNC）2 ]（PF 6）2（6：M = Pt，R =二甲苯基（Xyl）; 7：M = Pd，R = mesityl（Mes））。d 10 Pt 0（RNC）2和Pd 0（RNC）2个被示出片段被插入到对Pt的Pt σ -键的复杂3通过光谱和X-射线晶体分析。3中未配位的膦单元使d 10金属位于三核阵列的中间位置。还通过[Pd]的反应制备了类似的A框架三铝配合物[Pd 3（μ- dPMP）2（RNC）2 ]（PF 6）2（8a：R = Xyl; 8b：R = Mes）。3（RNC）8 ]（PF 6）2 与dPMP。
• Labile coordination of bis(diphenylphosphinomethyl) phenylphosphine in di- and trinuclear palladium and platinum complexes containing ortho-substituted aromatic isocyanide
  作者：Yasuhiro Yamamoto、Tomoaki Tanase、Hirokazu Ukaji、Masaru Hasegawa、Toshiaki Igoshi、Kazuhiro Yoshimura

  DOI：10.1016/0022-328x(95)05635-3

  日期：1995.8

  Reaction of [Pd-2(RNC)(6)](2+) with (Ph(2)PCH(2)),PPh (dpmp) gave [Pd-2(dpmp)(2)(RNC)(2)](2+) 1, in which dpmp ligands acted as chelating ligands. Thermal reaction of 1 underwent an elimination of isocyanide and change of a coordination mode of the dpmp ligands to give [Pd-2(dpmp)(2)(RNC)](2+) 2. Two kinds of new dimeric complexes [Pt-2(dpmp)(2)(RNC)(2)](2+) (4, 5) were obtained from [Pt-2(RNC)(6)](2+) and dpmp, in which dpmp ligands acted as bi- and tridentate ligand to bridge a metal-metal bond. Compounds 4 and 5 are interconvertible. Reaction of 5 with M(3)(RNC)(6) (M = Pt, Pd) gave a linear home- or hetero trinuclear complex, [Pt(2)M(dpmp)(2)(RNC)(2)](2+) (6, 7).
• Hexapalladium cluster: Unique cluster construction reaction of cyclic Pd3(CNC6H3Me2-2,6)6 and linear [Pd3(CNC6H3Me2-2,6)8]2+
  作者：Masato Ohashi、Jianjun Yi、Daisuke Shimizu、Tsuneaki Yamagata、Takashi Ohshima、Kazushi Mashima

  DOI：10.1016/j.jorganchem.2006.01.030

  日期：2006.5

  tReaction of a triangle Pd(0) complex, Pd-3(CNXyl)(6) (1; Xyl = 2,6-C6H3Me2), with a dicationic linear trinuclear complex [Pd-3(CNXyl)(8)][PF6](2) (3) afforded a dicationic hexapalladium complex [Pd-6(CNXyl)(12)][PF6](2) (4), while the reaction of I with a dicationic dinuclear complex [Pd-2(CNXyl)(6)][PF6](2) (2) resulted in the formation of 3. The molecular structure of the complex 4 was determined by X-ray crystallography and spectroscopic analysis. (c) 2006 Elsevier B.V. All rights reserved.
• Preparation of 1,1′-bis[(diphenylphosphino)methyl]ferrocene and its transition-metal complexes
  作者：Yasuhiro Yamamoto、Tomoaki Tanase、Idumi Mori、Yasuho Nakamura

  DOI：10.1039/dt9940003191

  日期：——

  1,1'-Bis[(diphenylphosphino)methyl]ferrocene (dpmf), prepared from 1,1'-bis(chloromethyl)ferrocene and LiPPh2, reacted with [PdCl2(MeCN)2] to give [Pd2Cl2(dpmf2] 1, and treatment of 1 with [Pd3(2,6-Me2C6H3NC)6] in a 1 : 0.66 ratio in the presence of NH4PF6 and 2,6-Me2C6H3NC produced a macrocyclic complex [Pd4(2,6-Me2C6H3NC)8(dpmf)2]4+.