(cis,cis,cis-1,5,9-cyclododecatriene)Cu(OTf) | 1142950-51-3

• 英文名称: (cis,cis,cis-1,5,9-cyclododecatriene)Cu(OTf)
• CAS: 1142950-51-3
• 化学式: C₁₃H₁₈CuF₃O₃S
• 分子量: 374.891
• InChiKey: NWPAEKMCYFBOCR-KVGTVSDOSA-M

反应信息

• 作为产物：
  描述：

  (R,R/S,Sη2,η2-1,5-hexadiene) copper(I) trifluoromethanesulfonate 、 1,5,9-cyclodecatriene 以 二氯甲烷 为溶剂， 以80%的产率得到(cis,cis,cis-1,5,9-cyclododecatriene)Cu(OTf)
  参考文献：
  名称：

  cis,cis,cis-1,5,9-Cyclododecatriene−Metal Complexes

  摘要：

  The ligand properties of cis,cis,cis-1,5,9-cyclododecatriene (c,c,c-cdt) have been explored. For the known (c,c,c-cdt)Ni (1b) and (c,c,c-cdt)(AgNO3)(3) (5) complexes and the new [(c,c,c-cdt)Cu(MeOH)]BF4 (6b), [(c,c,c-cdt)Cu][Al{OC(CF3)(3)}(4)] (6d), and ('BU2PC2H4P'Bu-2)Ni('eta(2)-c,c,c-cdt) (7b) complexes, the molecular structures have been determined. The c,c,c-cdt ligand in 5 and 7b retains the C-2 symmetrical helical conformation of the free c,c,c-cdt, whereas in 1b and 6b,d, it assumes a C-3 symmetrical ratchet conformation. The coordination geometry of the metal in 6b is tetrahedral, and it is trigonal pyramidal in 1b and 6d. Details of the synthesis and chemical and spectroscopic properties of the complexes are reported.

  DOI：

  10.1021/om7004172