trans-carbonyl(pentafluorophenyl-C)bis[(pentafluorophenyl)diphenylphosphine-P]iridium(I) | 220044-69-9

• 英文名称: trans-carbonyl(pentafluorophenyl-C)bis[(pentafluorophenyl)diphenylphosphine-P]iridium(I)
• CAS: 220044-69-9
• 化学式: C₄₃H₂₀F₁₅IrOP₂
• 分子量: 1091.77
• InChiKey: FYMACSFBKLHYMT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  mer-[IrF3(CO)((pentafluorophenyl)diphenylphosphine)2] 以 二氯甲烷-D2 为溶剂， 生成 trans-carbonyl(pentafluorophenyl-C)bis[(pentafluorophenyl)diphenylphosphine-P]iridium(I)
  参考文献：
  名称：

  trans-Carbonyl(pentafluorophenyl-C)bis[(pentafluorophenyl)diphenylphosphine-P]iridium(I)

  摘要：

  In trans-[Ir(C6F5){P(C6F5)(C6H5)(2)}(2)(CO)], the Ir-P and Ir-C distances are comparable to those of thr triphenylphosphine analogue. F ... F interactions appear to dominate the configuration, resulting in virtually eclipsed C6F5(Ir) and C6F5(P) rings.

  DOI：

  10.1107/s0108270198008063