-ferrocenyl-2,4-ditrimethylsilylbenzene | 1411645-89-0

• 英文名称: -ferrocenyl-2,4-ditrimethylsilylbenzene
• CAS: 1411645-89-0
• 化学式: C₂₂H₃₀FeSi₂
• 分子量: 406.498
• InChiKey: SBWLCSYMEZVCHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Co2(CO)6( 2-ferrocenylacetylene) 、 三甲基乙炔基硅 以 1,4-二氧六环 为溶剂， 反应 4.0h， 以68.4%的产率得到-ferrocenyl-2,4-ditrimethylsilylbenzene
  参考文献：
  名称：

  An effective method for the synthesis of monoferrocenylbenzene derivatives

  摘要：

  Three new ferrocenylbenzene derivatives, 1-ferrocenyl-2,3,4,5-tetramethylbenzene (1), 1-ferrocenyl-2,4-diphenylbenzene (2), and 1-ferrocenyl-2,4-ditrimethylsilylbenzene (3), were synthesized by cycloaddition of ferrocenylacetylene cobalt cluster with different alkynes and characterized by elemental analysis, FT-IR, NMR, and MS. The molecular structures of 2 and 3 were identified by single-crystal X-ray diffraction. The oxidation potentials of ferrocenyl unit in these compounds were investigated by cyclic voltammetry and theoretical calculations. The results indicated that the electron-donating or electron-withdrawing effect of substituents on the central phenyl was the key factor that influenced the oxidation potential of the ferrocenyl unit.

  DOI：

  10.1080/00958972.2012.732696