dicopper(II)(4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine)Cl4 | 1073937-81-1

• 英文名称: dicopper(II)(4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine)Cl4
• CAS: 1073937-81-1
• 化学式: C₂₄H₂₀Cl₄Cu₂N₆
• 分子量: 661.367
• InChiKey: GPYDDYOHOUPRNK-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine 以 乙醇 为溶剂， 以88%的产率得到dicopper(II)(4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine)Cl4
  参考文献：
  名称：

  Cu(II) complexes with 4,6-bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and catalytic activity in ethylene polymerization reaction

  摘要：

  The Cu(II) complexes with 4,6-bis(3,5-dimethyl-]H-pyrazole-1-yl)pyrimidine (0) and 4-(3,5-di dimethyl-1H-pyrazole-1-y1)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine (L-2) of the composition (CuLBr4)-Br-1 and Cu-2,L(2)A(4) (A = Cl, Br), respectively, were synthesized and studied by IR and magnetochemical methods. The molecular structure of the complexes is likely to be binuclear. In the presence of cocatalysts methylaluminoxane and triisobutylaluminium, the title complexes exhibit catalytic activity in the ethylene polymerization reaction.

  DOI：

  10.1134/s107032840708009x