| 198065-42-8

• CAS: 198065-42-8
• 化学式: BF₄*C₃₀H₂₆CrNO₄
• 分子量: 603.341
• InChiKey: FKTWTTAWVQREDG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 三乙胺 作用下， 以 not given 为溶剂， 生成 Carbon monoxide;chromium;1,2,3-triphenyl-5-azoniaspiro[4.5]deca-1,3-dien-4-olate
  参考文献：
  名称：

  Aminocarbene complexes of chromium. VII. Modification of the reactivity of nitrogen—ylide complexes derived therefrom upon removal of the metal

  摘要：

  The nitrogen-ylide complex 3 reacted with HBF4 to give in high yield the fluoroborate complex 6 which upon UV irradiation in the presence of O-2 led to the metal-free fluoroborates 7 and 8 fully characterized by X-ray crystallography; deprotonation of 7 in the presence of trace amount of water led instantaneously, upon hydrolysis, to the lactone 11, whereas deprotonation of 8 in the presence of ethanol gave the aminoester 12. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00017-x
• 作为产物：
  描述：

  tetrafluoroboric acid 、 Carbon monoxide;chromium;1,2,3-triphenyl-5-azoniaspiro[4.5]deca-1,3-dien-4-olate 以 乙醚 、 二氯甲烷 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Aminocarbene complexes of chromium. VII. Modification of the reactivity of nitrogen—ylide complexes derived therefrom upon removal of the metal

  摘要：

  The nitrogen-ylide complex 3 reacted with HBF4 to give in high yield the fluoroborate complex 6 which upon UV irradiation in the presence of O-2 led to the metal-free fluoroborates 7 and 8 fully characterized by X-ray crystallography; deprotonation of 7 in the presence of trace amount of water led instantaneously, upon hydrolysis, to the lactone 11, whereas deprotonation of 8 in the presence of ethanol gave the aminoester 12. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00017-x