[(η(6)-C6H6)Ru(NCMe)(C6H4-2-C5H4N)]PF6 | 228701-50-6

• 英文名称: [(η(6)-C6H6)Ru(NCMe)(C6H4-2-C5H4N)]PF6
• CAS: 228701-50-6
• 化学式: C₁₉H₁₇N₂Ru*F₆P
• 分子量: 519.392
• InChiKey: MLOJPLLTPYJKIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 [Ru(η6-C6H6)(C,N-2-(2-pyridinyl)phenyl-H)Cl] 以 乙腈 为溶剂， 反应 2.0h， 以70%的产率得到[(η(6)-C6H6)Ru(NCMe)(C6H4-2-C5H4N)]PF6
  参考文献：
  名称：

  Synthesis and comparative behavior of ruthena(II)cycles bearing benzene ligand in the radical polymerization of styrene and vinyl acetate

  摘要：

  A series of half-sandwich ruthenium(II) complexes of the type [Ru(eta(6)-C6H6)(NnC)LIPF6 (L = PPh3, P(nBu)(3), SbPh3, MeCN), bearing cyclometalated N,N-dimethylbenzylamine (la d) and 2-phenylpyridine (2a -d) moieties, has been efficiently prepared by ligand substitution. The molecular structures of the new compounds were unequivocally determined by single-crystal X-ray diffraction. The catalytic activity of the complexes in the radical polymerizations of styrene and vinyl acetate was evaluated, and a comparative structure activity analysis was performed. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2015.10.013