ammonium oxofluorenate | 71179-72-1

• 英文名称: ammonium oxofluorenate
• 英文别名: ammonium oxotrifluorotitanate
• CAS: 71179-72-1
• 化学式: F₃OTi*H₄N
• 分子量: 138.913
• InChiKey: HZHVIEAMGLZAEH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium oxofluorenate 生成 dioxide titanium
  参考文献：
  名称：

  三氟钛酸铵：形态控制和向锐钛矿型 TiO2 的转化

  摘要：

  在非离子表面活性剂存在下，由含有 (NH4)(2)TiF6 和 H3BO3 的水溶液合成了均匀的三氟钛酸铵 (NH4TiOF3) 介晶。通过电子显微镜技术检查了各种反应条件对 NH4TiOF3 介晶形貌的影响。结果表明，静态溶液、高表面活性剂浓度和低反应温度促进了形状规则的均匀NH4TiOF3介晶的形成。通过在大气中烧结，NH4TiOF3 介晶转变为锐钛矿型 TiO2，由于其原子结构相似，其保留了 NH4TiOF3 前体的原始形状。(c) 2008 WILEY-VCH Verlag GmbH & Co. KGaA，魏因海姆

  DOI：

  10.1002/pssa.200879447
• 作为产物：
  描述：

  ammonium hexafluorotitanate 在 C₁₆H₃₃(OCH₂CH₂)20OH or C₁₆H₃₃(OCH₂CH₂)100OH 、 air 、 H₂BO₃ 作用下， 以 not given 为溶剂， 生成 ammonium oxofluorenate
  参考文献：
  名称：

  Uniform NH₄TiOF₃mesocrystals prepared by an ambient temperature self-assembly process and their topotaxial conversion to anatase

  摘要：

  我们首次描述了一种简单的常温表面活性剂介导的NH4TiOF3无机中晶体的合成方法，以及通过洗涤或退火使其转化为锐钛矿中晶体的显著的顶轴转化。

  DOI：

  10.1039/b611476h

文献信息

• ——
  作者：N. M. Laptash、E. B. Merkulov、I. G. Maslennikova

  DOI：10.1023/a:1010105024143

  日期：——

  The thermal behaviour of ammonium oxofluorotitanates (NH4)(3)TiOF5, (NH4)(2)TiOF4 and NH4TiOF3 was investigated by thermoanalytical, X-ray and IR spectroscopic methods. The first decomposition stages under quasi-isobaric conditions are characterized by the formation of (NH4)(2)TiF6 and ammonium oxofluorotitanate with the less content of ammonium and fluorine than in the initial compound. The decomposition process is accompanied by the Ti(IV) reducing due to ammonia evolved. The new ammonium oxofluorotitanate of high volatility was isolated and characterized. Ammonium-containing non-stoichiometric titanium oxyfluorides are the final products of thermal decomposition of ammonium oxofluorotitanates.
• A Facile Synthesis of Uniform NH₄TiOF₃ Mesocrystals and Their Conversion to TiO₂ Mesocrystals
  作者：Lei Zhou、David Smyth-Boyle、Paul O'Brien

  DOI：10.1021/ja076187c

  日期：2008.1.30

  Uniform mesocrystals of TiO2 (anatase) have been prepared from mesocrystals of NH4TiOF3NH4TiOF3 was synthesized from an aqueous solution containing (NH4)(2)TiF6 and H3BO3 in the presence of a nonionic surfactant Brij 56, Brij 58, or Brij 700, at low temperatures. The exterior shapes of NH4TiOF3 mesocrystals can be tuned by adjusting the reagent concentration, reaction time, reaction temperature, and rate of stirring. The formation of the NH4TiOF3 mesocrystals proceeds via a self-assembly process involving nonclassical crystal growth. By sintering in air at 450 degrees C, or washing with H3BO3 solution at ambient temperatures, the NH4TiOF3 mesocrystals can be converted to mesocrystals of TiO2 (anatase), and the original architecture is retained.