| 182263-13-4

• CAS: 182263-13-4
• 化学式: C₇₇H₁₀₇ClCoN₂₁O₂₀
• 分子量: 1741.27
• InChiKey: AIIAQVJKSNTKFR-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  、 trifluoroborane diethyl ether 以 乙腈 为溶剂， 以67.2%的产率得到
  参考文献：
  名称：

  The synthesis and characterization of novel vicinal dioxime and its cobalt(III) complexes containing 17-membered macrocyclic ionophores

  摘要：

  A novel (E, E)-dioxime (LH(2)) containing triaza-dioxa macrocyclic ionophores has been synthesized from the reaction of 2,3-(4'-aminobenzo)-1,4-dioxa-6,16-dioxo-11-azamethyl-7,15- diazacycloheptadecane-2-ene (4) which has been prepared from 2,3-(4'nitrobenzo)-1,4-dioxa-6, 16-dioxo-11-azamethyl-7,15-diazacycloheptadecane (3) and (E, E)-dichloroglyoxime (5). The cobalt(III) complex of LH(2) has been obtained with L' = pyridine and chloride ion as axial ligands. The BF2+-capped cobalt(III) complex is achieved by reacting the hydrogen bridged cobalt(III) complex with boron trifluoride etherate. The structures of the dioxime and its complexes are proposed according to elemental analysis, H-1 and C-13 NMR, IR and mass spectral data. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0277-5387(96)00143-x
• 作为产物：
  描述：

  吡啶 、 cobalt(II) chloride hexahydrate 、 N,N'-bis[2,3-(4'-aminobenzo)-1,4-dioxa-6,16-dioxo-11-azamethyl-7,15-diazacycloheptadecane-2-ene]-diaminoglyoxime 以 乙醇 为溶剂， 以74.7%的产率得到
  参考文献：
  名称：

  The synthesis and characterization of novel vicinal dioxime and its cobalt(III) complexes containing 17-membered macrocyclic ionophores

  摘要：

  A novel (E, E)-dioxime (LH(2)) containing triaza-dioxa macrocyclic ionophores has been synthesized from the reaction of 2,3-(4'-aminobenzo)-1,4-dioxa-6,16-dioxo-11-azamethyl-7,15- diazacycloheptadecane-2-ene (4) which has been prepared from 2,3-(4'nitrobenzo)-1,4-dioxa-6, 16-dioxo-11-azamethyl-7,15-diazacycloheptadecane (3) and (E, E)-dichloroglyoxime (5). The cobalt(III) complex of LH(2) has been obtained with L' = pyridine and chloride ion as axial ligands. The BF2+-capped cobalt(III) complex is achieved by reacting the hydrogen bridged cobalt(III) complex with boron trifluoride etherate. The structures of the dioxime and its complexes are proposed according to elemental analysis, H-1 and C-13 NMR, IR and mass spectral data. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0277-5387(96)00143-x