((tris(1H-pyrazolyl)borate)MoO)(μ2-O)2(MoO(tris(1H-pyrazolyl)borate)) | 101347-50-6

• 英文名称: ((tris(1H-pyrazolyl)borate)MoO)(μ2-O)2(MoO(tris(1H-pyrazolyl)borate))
• 英文别名: (hydrotripyrazolylborate)2Mo2(O)2(μ-O)2；((tris(1H-pyrazolyl)borate)MoO)(μ₂-O)₂(MoO(tris(1H-pyrazolyl)borate))；(TpMoO)(μ₂-O)₂(MoOTp)
• CAS: 101347-50-6
• 化学式: C₁₈H₂₀B₂Mo₂N₁₂O₄
• 分子量: 681.937
• InChiKey: HCXPKZRGQDFNBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ((tris(1H-pyrazolyl)borate)MoO)(μ2-O)2(MoO(tris(1H-pyrazolyl)borate)) 在 HCl 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Lincoln, Sandra; Koch, Stephen A., Inorganic Chemistry, 1986, vol. 25, # 10, p. 1594 - 1602

  摘要：

  DOI：
• 作为产物：
  描述：

  五氯化钼 、 三吡唑啉基硼氢钾 以 盐酸 为溶剂， 以30%的产率得到((tris(1H-pyrazolyl)borate)MoO)(μ2-O)2(MoO(tris(1H-pyrazolyl)borate))
  参考文献：
  名称：

  Lincoln, Sandra; Koch, Stephen A., Inorganic Chemistry, 1986, vol. 25, # 10, p. 1594 - 1602

  摘要：

  DOI：

文献信息

• Two novel oxomolybdenum(V)-trispyrazolylborate complexes: Synthesis, structure, and catalytic performance in the cyclohexane oxidation
  作者：Xin Liu、Na Xing、Jian Song、Qiong Wu、Zhidan Yan、Yan Zhang、Yongheng Xing

  DOI：10.1016/j.poly.2015.09.056

  日期：2015.12

  Two novel oxomolybdenum(V)-trispyrazolylborate complexes [(TpMoO)(mu(2)-O)(2)(MoOTp)](Tp = tris (pyrazolyl)borate) (1) and [(Tp(4I)MoOCl)(mu-O)(MoOClTp(4I))](Tp(4I) = tris(4-iodinpyrazolyl)borate) (2) were synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. Their catalytic performances in cyclohexane (Cy) oxidation were studied. It is found that the catalytic performances of molybdenum(V) complexes 1 and 2 were far more better than the molybdenum(VI) complexes with the similar structure. The influence of the amount of H2O2, HNO3 and the solvents on the Cy oxidation were investigated too. (C) 2015 Elsevier Ltd. All rights reserved.