| 176313-43-2

• CAS: 176313-43-2
• 化学式: C₁₆H₄₂Al₂P₂
• 分子量: 350.42
• InChiKey: IGCQRMRGQWMORW-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,2-bis(tert-butylphosphino)ethane 、 三甲基铝 以 正己烷 为溶剂， 以49%的产率得到
  参考文献：
  名称：

  Use of Chelating Diphosphines To Prepare New Phosphido Clusters of Aluminum and Gallium

  摘要：

  Novel phosphido cluster complexes of formula (Me(2)M)(4)(mu-(1,2-PR)(2)C6H4)(2) (M = Al, R = Me (1); M = Ga, R = t-Bu (2)) result when the chelating diphosphine ligand 1,2-bis(alkylphosphino)benzene is mixed with trialkylaluminum and -gallium reagents. When the potentially chelating ligand 1,2-bis(tert-butylphosphino)ethane is mixed with 2 equiv of AlMe(3) under the same conditions, the secondary phosphine bis-adduct complex Me(3)Al . PH(t-Bu)CH2CH2(t-Bu)HP . AlMe(3) (3) is formed.

  DOI：

  10.1021/om960122t