| 182317-81-3

• CAS: 182317-81-3
• 化学式: C₂₆H₆₂AlLiO₄Si₃
• 分子量: 556.955
• InChiKey: PWRQCIGFRNKRJR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 叔丁醇 以 甲苯 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Organotrialkoxy- and Organotrifluoroaluminates:  Crystal Structures of Li[(Me₃Si)₃CAlX₃]·OC₄H₈ (X = ^tBuO, F)

  摘要：

  Reactions of the organotrihydroaluminate Li-[(Me(3)Si)(3)CAlH3]. 2THF, (THF = tetrahydrofuran) with the protic reagents (t)BuOH or HF in toluene yield the novel compounds Li[(Me(3)Si)(3)CAlX(3)]. THF, X = (t)BuO or F, which crystallize as a monomer and a tetramer, respectively. Multinuclear NMR measurements on the latter show that the tetrameric structure is broken down in THF but preserved in benzene; the [(Me(3)Si)(3)CAlF3] fragments rotate on the NMR time scale about the body diagonal of the Al4Li4 cube.

  DOI：

  10.1021/om960496m