| 187155-68-6

• CAS: 187155-68-6
• 化学式: C₄₂H₉₈Ce₄O₁₅
• 分子量: 1403.71
• InChiKey: MMIOMLMSDHAONE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Ce₂(OiPr)₈(HOⁱPr)₂ 以 neat (no solvent) 为溶剂， 以43%的产率得到
  参考文献：
  名称：

  Facile thermal desolvation of Ce2(OPri)8(PriOH)2: Characterization and molecular structure of Ce4(μ4-O)(μ3-OPri)(μ-OPri)4(OPri)8

  摘要：

  Thermal treatment of Ce-2(OPri)(8)((PrOH)-O-i)(2) yielded Ce-4(mu(4)-O)(OPri)(14) by desolvation under mild conditions. The tetranuclear oxoalkoxide has been characterized by elemental analysis, FT-IR, H-1 NMR and X-ray diffraction. The structure is described as [Ce-4(mu(4)-O)(mu(3)-OPri)(2)(mu-OPri)(4)(OPri)(8)]. The Ce-4(mu(4)-O) core corresponds to a distorted flattened tetrahedron, with two hexa- and two hepta-coordinated metals. The Ce-O bond lengths spread over the range 2.03(2) to 2.54(1) Angstrom, and follow the order Ce-OR < Ce-mu OR < Ce mu(3)-OR. Copyright (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00378-6