PtCl2[N,Se-Ph2(2-C5H4N)PSe] | 620160-13-6

• 英文名称: PtCl2[N,Se-Ph2(2-C5H4N)PSe]
• CAS: 620160-13-6
• 化学式: C₁₇H₁₄Cl₂NPPtSe
• 分子量: 608.225
• InChiKey: IQBKNVPRFZLCNH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(benzonitrile)dichloroplatinum(II) 、 diphenyl(2-pyridyl)phosphine selenide 以 二氯甲烷 为溶剂， 生成 PtCl2[N,Se-Ph2(2-C5H4N)PSe]
  参考文献：
  名称：

  Reactivity of Ph2(2-C5H4N)PSe towards Ru3(CO)12 and mononuclear MCl2(PhCN)2 (M=Pd or Pt) complexes

  摘要：

  The behavior of the Ph-2(2-C5H4N)PSe ligand in the reactions with Ru-3(CO)(12) and the mononuclear complexes MCl2(PhCN)(2) (M=Pd or Pt) has been investigated. The reaction with Ru-3(CO)(12) is characterized by P=Se bond cleavage, affording the 48-electron compound [Ru-3(mu(3)-Se)(mu-PPh2)(2)(mu-C5H4N)(mu(3)-C5H4N)(CO)(6)] (1), the open triangular 50-electron nido clusters [Ru-3(mu(3)-Se),(CO)(9-n) {P(2-C5H4N)Ph-2}] (2 and 3, for n=1 and 2, respectively) and the octahedral 62-electron closo cluster [Ru-4(mu(4)-Se)(2)(CO){mu-P, N-Ph-2(2-C5H4N)P}] (4). The cluster 1 derives by the multiple fragmentation of two phosphine ligands on the metal triangle involving the P=Se and P-C bond cleavages. The molecular structure of 4 shows a short Ru...P non-bonding separation that can be viewed as a preliminary step towards the P-C bond cleavage. In the reactions with MCl2(PhCN)(2) (M=Pd, Pt) Ph-2(2-C5H4N)PSe remains intact affording mononuclear neutral complexes of the type MCl2{N,Se-Ph-2(2-C5H4N)PSe}. The crystal structure of the palladium derivative 5 has been determined by X-ray diffraction methods. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01518-9