| 199789-13-4

• CAS: 199789-13-4
• 化学式: C₁₆H₂₂O₂Ru
• 分子量: 347.419
• InChiKey: LULFVNRNLMFAOK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1.1'-Ru(C5H4(COCH3))2 在 甲基锂 作用下， 以 乙醚 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Conformational analysis of the [(C5H4CR'R")2M]2+ dications (M=Ru, Os) as a tool for determining their onium or dicarbocation structure

  摘要：

  The [(Me2CC5H4)(2)M](2+) and [(Me(H)CC5H4)(2)M](2+) dications (M = Ru, Os) were generated and their precursors, dicarbinols, were synthesized. H-1 NMR spectral analysis showed that the former dications have a dicarbocation structure. For the [(Me(H)CC5H4)(2)M](2+) dications, the energies of both the onium and dicarbocation structures are close, and compounds of both types can be simultaneously observed in solution.

  DOI：

  10.1007/bf02505686