| 168333-12-8

• CAS: 168333-12-8
• 化学式: C₂₉H₂₃ClN₅Ru*F₆P
• 分子量: 723.022
• InChiKey: ACVMXYDUKVTPRD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  六氟磷酸银 、 、 乙腈 在 ammonium hexafluorophosphate 作用下， 以 乙二醇甲醚 、 水 为溶剂， 生成
  参考文献：
  名称：

  Multistep CO2 Reduction Catalyzed by [Ru(bpy)2(qu)(CO)]2+ (bpy = 2,2'-Bipyridine, qu = Quinoline). Double Methylation of the Carbonyl Moiety Resulting from Reductive Disproportionation of CO2

  摘要：

  The title complexes catalyze the reductive disproportionation of CO2 forming CO and CO32- in the electrochemical CO2 reduction in CH3CN with LiBF4. The same reduction in the presence of Me(4)NBF(4) instead of LiBF4 produces CH3C(O)CH3 and CH3C(O)CH2COO- in addition to HCOO- and CO in CH3CN/DMSO (1:1, v/v). In this reaction Me(4)N(+) functions as the methylation agent of the carbonyl moiety resulting from the reductive disproportionation of CO2. The produced CH3C(O)CH3 undergoes the abstraction of its ex-proton and subsequent carboxylation to afford CH3C(O)CH2COO-.

  DOI：

  10.1021/om00011a031
• 作为产物：
  描述：

  喹啉 、 hexafluorophosphoric acid 、 顺-双(2,2-二吡啶)二氯化钌(II) 水合物 以 乙醇 、 水 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Multistep CO2 Reduction Catalyzed by [Ru(bpy)2(qu)(CO)]2+ (bpy = 2,2'-Bipyridine, qu = Quinoline). Double Methylation of the Carbonyl Moiety Resulting from Reductive Disproportionation of CO2

  摘要：

  The title complexes catalyze the reductive disproportionation of CO2 forming CO and CO32- in the electrochemical CO2 reduction in CH3CN with LiBF4. The same reduction in the presence of Me(4)NBF(4) instead of LiBF4 produces CH3C(O)CH3 and CH3C(O)CH2COO- in addition to HCOO- and CO in CH3CN/DMSO (1:1, v/v). In this reaction Me(4)N(+) functions as the methylation agent of the carbonyl moiety resulting from the reductive disproportionation of CO2. The produced CH3C(O)CH3 undergoes the abstraction of its ex-proton and subsequent carboxylation to afford CH3C(O)CH2COO-.

  DOI：

  10.1021/om00011a031