| 19414-02-9

• CAS: 19414-02-9
• 化学式: C₅H₁₁N*C₆NO₅W*H
• 分子量: 436.077
• InChiKey: DJIODZBAFJDOTL-UHFFFAOYSA-O

反应信息

• 作为产物：
  描述：

  哌啶 、 (η(5)-C5H5)(CO)2FeNCW(CO)5 以 not given 为溶剂， 生成 cyclopentadienyl iron(II) dicarbonyl dimer 、
  参考文献：
  名称：

  Synthesis and spectroscopic properties of heteropolynuclear cyano-bridged complexes

  摘要：

  The heteropolynuclear cyano-bridged complexes [(C(5)H(5))Fe(CO)(CNMLn)(CNM'L'n)], {MLn = M'L'n = (C(5)H(5))Fe(CO)(2) or W(CO)(5); MLn = (C(5)H(5))Fe(CO)(2), M'L'n = W(CO)(5)} and mixed isocyanide complexes [(C(5)H(5))Fe(CO)(CNMLn)(CNR)], {MLn = W(CO)(5), R = CPh(3); MLn = (C(5)H(5))Fe(CO)(2), R = CH(3)} have been obtained by metallation or alkylation of the two terminal CN ligands of K[(C(5)H(5))Fe(CO)(CN)(2)]. Comparison of the bonding properties of the CNMLn and CNR ligands, based upon their relevant spectroscopic data, are discussed. Furthermore, two new isomeric heterobinuclear cyano-bridged complexes of the form [(C(5)H(5))(CO)(2)FeCNW(CO)(5)] and [(C(5)H(5))(CO)(2)FeNCW(CO)(5)] have been synthesized and fully characterized by spectroscopic techniques. Finally the reactions with nucleophiles of the last two compounds have been also examined. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00352-5