[Au(C6F5)3(3-ferrocenylpyridine)] | 259210-79-2

• 英文名称: [Au(C6F5)3(3-ferrocenylpyridine)]
• CAS: 259210-79-2
• 化学式: C₃₃H₁₃AuF₁₅FeN
• 分子量: 961.262
• InChiKey: HEHRXNFDPSWLDR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (pyridin-3-yl)ferrocene 、 tris(pentafluorophenyl)(OEt2)gold(I) 以 乙醚 为溶剂， 以80%的产率得到[Au(C6F5)3(3-ferrocenylpyridine)]
  参考文献：
  名称：

  Synthesis, structure and redox behaviour of gold and silver complexes with 3-ferrocenylpyridine

  摘要：

  3-Ferrocenylpyridine (Fcpy) reacts with gold(I) derivatives to afford neutral, [AuR(Fcpy)] (R = Cl, C6F5), or cationic complexes, [Au(Fcpy)(PPh3)]OTf. Reaction with [Au(C6F5)(2)(OEt2)(2)]ClO4 or [Au(C6F5)(3)(OEt2)] gives the gold(III) complexes [Au(C6F5)(2)(Fcpy)(2)]ClO4 or [Au(C6F5)(3)(Fcpy)], respectively. The silver derivatives [Ag(Fcpy)(PPh3)]OTf and [Ag(OTf)(Fcpy)(2)] have also been synthesised. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00547-1