(2-ferrocenylethyl)trimethylammonium perchlorate | 163462-41-7

• 英文名称: (2-ferrocenylethyl)trimethylammonium perchlorate
• CAS: 163462-41-7
• 化学式: C₁₅H₂₂FeN*ClO₄
• 分子量: 371.644
• InChiKey: WRFKWPSNMVPRNS-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  (2-ferrocenylethyl)trimethylammonium iodide 在 perchloric acid 作用下， 以 水 为溶剂， 以25%的产率得到(2-ferrocenylethyl)trimethylammonium perchlorate
  参考文献：
  名称：

  Electrochemical Measurements of Anisotropic Diffusion in Thin Lyotropic Liquid Crystal Films Using Interdigitated Array Electrodes

  摘要：

  A new application of interdigitated array (IDA) electrodes is described for diffusion measurements of electrochemical probes dissolved in thin, lyotropic liquid crystalline films. The liquid crystal is a solution of 32% (w/w) Lithium 4-trans-n-pentyI cyclohexanoate (Li5CH) in water, which can be prepared as well-ordered films of thickness less than ca. 12 mu m. Apparent diffusion coefficients (D-APP) Of the electrochemical probes are calculated from steady-state currents of generator/collector voltammograms. The diffusional anisotropy, measured parallel and perpendicular to the liquid crystal director, increases with increasing hydrophobicity of the probes. A simplified model has been developed to explain the diffusional anisotropy of hydrophobic probes in the ordered film. The transition temperature of the liquid crystal is determined from an activation plot of D-APP for 1,1'-dimethylferrocene.

  DOI：

  10.1021/j100021a055