[CrCl2(1,10-phenathroline)2]ClO4 * H2O | 164411-90-9

• 英文名称: [CrCl2(1,10-phenathroline)2]ClO4 * H2O
• CAS: 164411-90-9
• 化学式: C₂₄H₁₆Cl₂CrN₄*ClO₄*H₂O
• 分子量: 600.786
• InChiKey: ZEBAXKWSKNBOKD-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  sodium perchlorate 、 chromium chloride hexahydrate 、 [Ag(1,10-phenanthroline)2]ClO4 * 2H2O 以 水 、 乙腈 为溶剂， 以50%的产率得到[CrCl2(1,10-phenathroline)2]ClO4 * H2O
  参考文献：
  名称：

  Convenient Approach to the Direct Syntheses of Chromium Complexes from Chromium(III) Chloride

  摘要：

  Efficient, new and direct synthetic routes for the syntheses of chromium complexes of some N,N-donors, based on the reactions of a chromium(III) chloride salt and silver(I) complexes of the corresponding ligands, have been described. It has been shown that syntheses of mixed-ligand complexes of desired compositions may easily be achieved by following these trans-metalation reaction routes. Comparison of the synthetic methodology with the reported methods has been noted.

  DOI：

  10.1021/ic00118a035