(η5-C5H5)[C6H5C(NSi(CH3)3)2]TiMe2 | 161566-39-8

• 英文名称: (η5-C5H5)[C6H5C(NSi(CH3)3)2]TiMe2
• 英文别名: [Ti(η-C5H5)(CPh(NSiMe3)2)Me2]
• CAS: 161566-39-8
• 化学式: C₂₀H₃₄N₂Si₂Ti
• 分子量: 406.554
• InChiKey: BQEBAKBKOAQRJU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  dichloro(cyclopentadienyl)(N,N'-bis-(trimethylsilyl)benzamidinato)titanum(IV) 、 甲基锂 以 乙醚 、 甲苯 为溶剂， 以62%的产率得到(η5-C5H5)[C6H5C(NSi(CH3)3)2]TiMe2
  参考文献：
  名称：

  Mono(η-cyclopentadienyl)benzamidinato alkyl compounds of titanium and zirconium

  摘要：

  The compounds [Zr(eta-C5H5){CPh(NSiMe(3))(2)}Cl-2], [{Zr(eta-C5H5)[CPh(NSiMe(3))(2)]Cl}(2){mu-CPh(NSiMe(3))(2)}] [{Zr(eta-C5H5)[CPh(NSiMe(3))(2)]Cl}(2)(mu-O)], [Zr(eta-C(5)R(5)){CPh(NSiMe(3))(2)}(CH(2)Ph)Cl] (R = H or Me), [Zr(eta-C(5)R(5)){CPh(NSiMe(3))(2)}(CH(2)Ph)(2)] (R = H or Me) and [M(eta-C(5)R(5)){CPh(NSiMe(3))(2)}Me(2)] (M = Zr, R = H or Me; M = Ti, R = H have been synthesized and the crystal structures of three of them) determined.

  DOI：

  10.1039/dt9950000217