| 159804-71-4

• CAS: 159804-71-4
• 化学式: Br₃Sn*CH₆N
• 分子量: 396.44
• InChiKey: PURGUWYDGBUOSZ-LADZBLSZSA-L

反应信息

• 作为产物：
  描述：

  、 tin(II) bromide 以 乙醇-D1 为溶剂， 生成
  参考文献：
  名称：

  Neutron-diffraction study of CD3ND3SnBr3: Semiconductor—insulator transition with orientational ordering

  摘要：

  Neutron-diffraction experiments were performed on the semiconductor (room-temperature) and insulator (195 K) phases of CD3ND3SnBr3 using a powder diffractometer at KENS. Rietveld refinement revealed fully disordered CD3ND3+ ions (rotating like a spherical shell) in the semiconductor phase (Pm3m, Z = 1, a = 5.899 Angstrom). The insulator phase has a rhombohedral structure with cell doubling in three directions (R3c or R $($) over bar$$ 3c, Z = 8, a = 11.767 Angstrom, alpha = 88.997 degrees), suggesting that the C-N axis of the CD3ND3+ ion is ordered along the crystallographic C-3 or ($) over bar 3 axis and the SnBr6 octahedron is distorted from the regular O-h symmetry.

  DOI：

  10.1016/0921-4526(95)00173-7