Co(ONC(Me)C(Me)NOH)2(methanesulfonyl)(pyridine) | 25162-57-6

• 英文名称: Co(ONC(Me)C(Me)NOH)2(methanesulfonyl)(pyridine)
• CAS: 25162-57-6
• 化学式: C₁₄H₂₂CoN₅O₆S
• 分子量: 447.418
• InChiKey: JKPLBWJHZCYUPP-DVTASQICSA-L

反应信息

• 作为产物：
  描述：

  Co(ONC(Me)C(Me)NOH)2((5-trimethylsilyl)pent-4-ynyl)(pyridine) 、 甲基磺酰氯 以 二氯甲烷 为溶剂， 以45%的产率得到Co(ONC(Me)C(Me)NOH)2(methanesulfonyl)(pyridine)
  参考文献：
  名称：

  Organocobaloximes in organic synthesis an unusual radical-dependent five-member cyclization

  摘要：

  Visible light photolysis of organocobaloximes R'C=C[CH2](3)-Co-III(dmgH)(2)Py 1-3 (R' = Ph, TMS, H) with radical trapping agents ArSO2Cl (Ar = Ph, 4-MeC6H4, 4-OMeC6H4, 4-BrC6H4, 6ClC(6)H(4)) and MeSO2Cl afford rearranged or non-rearranged organic products depending on the R' group. 2-Phenylcyclopentenyl sulfones 4a-4f have been obtained exclusively in the case of cobaloxime 1. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(96)06801-5