((hexyl)HC(N-methyl-imidazol-2-yl)2)Pd(Cl)Me | 628727-82-2

• 英文名称: ((hexyl)HC(N-methyl-imidazol-2-yl)2)Pd(Cl)Me
• CAS: 628727-82-2
• 化学式: C₁₆H₂₇ClN₄Pd
• 分子量: 417.29
• InChiKey: OXNHZCJHKZTWSG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ((hexyl)HC(N-methyl-imidazol-2-yl)2)Pd(Cl)Me 以 further solvent(s) 为溶剂， 生成 钯
  参考文献：
  名称：

  Photochemical synthesis of a palladium dichloromethyl complex, {(hexyl)HC(N-methyl-imidazol-2-yl)2}Pd(CHCl2)Cl.

  摘要：

  The reaction of (hexyl)HC(mim)(2) (1, mim = N-methyl-imidazol-2-yl) with (cod)PdMeCl in C6H6 yields {(hex-yl)HC(mim)(2)}Pd(Me)Cl (3). The photochemical reaction of 3 with CH2Cl2 at 23 degreesC in ambient room light yields {(hex-yl)HC(mim)(2)}Pd(CHCl2)Cl (4). It is proposed that this reaction proceeds by homolytic scission of the Pd-Me bond of 3. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00693-4
• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 (hexyl)HC(N-methyl-imidazol-2-yl)2 以 苯 为溶剂， 以94%的产率得到((hexyl)HC(N-methyl-imidazol-2-yl)2)Pd(Cl)Me
  参考文献：
  名称：

  Photochemical synthesis of a palladium dichloromethyl complex, {(hexyl)HC(N-methyl-imidazol-2-yl)2}Pd(CHCl2)Cl.

  摘要：

  The reaction of (hexyl)HC(mim)(2) (1, mim = N-methyl-imidazol-2-yl) with (cod)PdMeCl in C6H6 yields {(hex-yl)HC(mim)(2)}Pd(Me)Cl (3). The photochemical reaction of 3 with CH2Cl2 at 23 degreesC in ambient room light yields {(hex-yl)HC(mim)(2)}Pd(CHCl2)Cl (4). It is proposed that this reaction proceeds by homolytic scission of the Pd-Me bond of 3. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00693-4