[Pd(bis((3-diphenylphosphino)propyl)sulfide)Cl]ClO4 | 193483-39-5

• 英文名称: [Pd(bis((3-diphenylphosphino)propyl)sulfide)Cl]ClO4
• CAS: 193483-39-5
• 化学式: C₃₀H₃₂ClP₂PdS*ClO₄
• 分子量: 727.921
• InChiKey: FFARYKHBTXKHQC-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  bis((3-diphenylphosphino)propyl)sulfide 、 sodium perchlorate 、 palladium dichloride 以 二氯甲烷 、 乙腈 为溶剂， 以70%的产率得到[Pd(bis((3-diphenylphosphino)propyl)sulfide)Cl]ClO4
  参考文献：
  名称：

  Syntheses and structures of palladium(II) and platinum(II) complexes with tridentate (Ph2PCH2CH2CH2)2S and its arsenic analogue

  摘要：

  A series of square-planar complexes [MLCl]ClO4 (M = Pd(II), Pt(II); L = bis(3-(diphenylphosphino) propyl) sulfide (psp), bis(3-(diphenylarsino) propyl) sulfide (asa)) have been prepared and characterized. The X-ray crystal structures of two of them have been determined: [Pd(psp)Cl]ClO4, P2(1)/c, a=12.519(2), b=15.766(2), c=16.501(2) Angstrom, beta=105.22(1)degrees, Z=4; and [Pt(asa)Cl]ClO4, P2(1)/c, a=12.583(5), b=16.007(6), c=16.549(6) Angstrom, beta=104.89(3)degrees, Z=4. In both structures, there is a conformational disorder between the chair and skew-boat orientation in one of the two six-membered chelate rings. The C-H ... O hydrogen bond between the hybrid ligand and the perchlorate counter ion that induces the conformational disorder is discussed.

  DOI：

  10.1016/s0020-1693(96)05552-1