(2-[(E)-(phenylimino)methyl]phenolato)2Re2(CO)6 | 1338380-27-0

• 英文名称: (2-[(E)-(phenylimino)methyl]phenolato)2Re2(CO)6
• CAS: 1338380-27-0
• 化学式: C₃₂H₂₀N₂O₈Re₂
• 分子量: 932.933
• InChiKey: HHGIEMIOVOVAPS-SRGBNRPFSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  五羰基氯铼(I) 、 Phenol, 2-[(E)-(phenylimino)methyl]- 以 甲苯 为溶剂， 以50%的产率得到(2-[(E)-(phenylimino)methyl]phenolato)2Re2(CO)6
  参考文献：
  名称：

  Center-symmetric dimeric Re(CO)3+ complexes with Schiff base derivatives of salicylic aldehyde

  摘要：

  A simple synthetic procedure (reaction between Re(CO)(5)Cl and 2-[(E)-(phenylimino)methyl]- or 2-[(E)-(n-propylimino)-methyl]-phenol) leads to novel dimeric Re-2(CO)(6)(N boolean AND O-)(2) complexes with the structures confirmed by means of X-ray crystallography. The obtained species have been characterized by means of elemental analysis, FT-IR, UV-VIS absorption, and EI-MS spectroscopy. The solvolysis experiments performed in dimethylsulfoxide solutions point to well pronounced stability of the investigated species. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.08.006