| 1283046-10-5

• CAS: 1283046-10-5
• 化学式: AuCl₄*C₁₀H₈AuCl₂N₂S
• 分子量: 794.904
• InChiKey: MPOKAUJMWZXNIW-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-吡啶基硫醚 、 sodium tetrachloroaurate(III) dihyrate 在 AgBF₄ 作用下， 以 乙腈 为溶剂， 以17.9%的产率得到
  参考文献：
  名称：

  A report describing the effect of di-2-pyridyl ligand architecture on the coordination properties with gold(III)

  摘要：

  In an effort to develop novel gold-based chemotherapies, gold(III) coordination complexes possessing a series of di-2-pyridyl ligands were targeted as synthetic products. It was found that di-2-pyridyl ligands linked by different groups exhibited varying coordination to gold(III). Di-2-pyridyl sulfide (DPS) exhibited bidentate binding to gold(III), and formed a complex ion with a gold tetrachloride counter ion {[(DPS)AuCl2] AuCl4; compound 3}; di-2-pyridyl ether (DPO) formed a neutral monodentate coordination complex with gold(III) {[(DPO)(AuCl3)]; compound 4}; and attempts to make a gold(III) complex with di-2-pyridyl ketone (DPK) were unsuccessful, as a complex ion possessing the protonated ligand and a gold tetrachloride anion was isolated {[HDPK][AuCl4]; compound 5}. Compounds 3-5 were structurally characterized using X-ray crystallography, which confirmed the different coordination environments around the gold(III) metal centers. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.052