| 191282-41-4

• CAS: 191282-41-4
• 化学式: C₈₁H₉₉Ga₉O₉
• 分子量: 1844.18
• InChiKey: ICKJXUJJBZZYQH-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 1,4-二氧六环 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of (MesGaO)₉ (Mes = Me₃C₆H₂) and Crystal Structure of the First Galloxane Comparable to Catalytically Active Aluminum Compounds

  摘要：

  The thermolysis of (Mes(2)GaOH)(2) . THF in toluene or 1,4-dioxane at 100 degrees C resulted in the formation of (MesGaO)(9) (1). A byproduct of this reaction is Mes(3)Ga. Compound 1 was characterized by electron impact mass spectroscopy and single-crystal X-ray structural analysis. The structure consists of two six-membered (MesGaO)(3) rings connected by three mu(2)-(MesGaO) units.

  DOI：

  10.1021/om970086d