| 169897-46-5

• CAS: 169897-46-5
• 化学式: C₃₇H₁₈ClF₁₂O₇P₂Rh
• 分子量: 1002.83
• InChiKey: KKJKUWPZBZKIMG-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 tris(2,6-difluorophenyl)phosphite 以 苯 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  Tris(2,6-difluorophenyl)phosphite complexes of platinum group metals: Structure of trans-PtCl2(PEt3){P(O-2,6-C6H3F2)3}

  摘要：

  The reactions between the fluorine-containing ligand tris(2,6-difluorophenyl)phosphite and the transition metal species [{eta(6)-1,4-CH3C6H4CH(CH3)(2)} RuCl2](2), [Cp*RhCl2](2), [RhCl(CO)(2)](2), [PtCl2(PEt(3))](2) and PtCl2 yield the complexes {eta(6)-1,4-CH3C6H4CH(CH3)(2)} RuCl2{P(O-2,6-C6H3F2)(3)}, Cp*RhCl2{P(O-2,6-C6H3F2)(3)}, trans-RhCl(CO {P(O-2,6-C6H3F2)(3)}(2), trans-PtCl2 (PEt(3)) {PO-2,6-C6H3F2)(3)} and trans-PtCl2{P(O-2,6-C6H3F2)(3)}(2), respectively. The molecular structure of trans-PtCl2(PEt(3)) {P(O-2,6-C6H3F2)(3)} has been determined by single-crystal X-ray crystallography.

  DOI：

  10.1016/0277-5387(95)00020-s