[PtHMe2(tris(2-pyridylmethyl)amine)]BF4 | 662112-56-3

• 英文名称: [PtHMe2(tris(2-pyridylmethyl)amine)]BF4
• CAS: 662112-56-3
• 化学式: BF₄*C₂₀H₂₅N₄Pt
• 分子量: 603.33
• InChiKey: XPUFWGWBDPHHBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrafluoroboric acid 、 [PtMe2(tris(2-pyridylmethyl)amine)] 以 氘代丙酮 为溶剂， 生成 [PtHMe2(tris(2-pyridylmethyl)amine)]BF4 、 [PtHMe2(tris(2-pyridylmethyl)amine)]BF4
  参考文献：
  名称：

  Dimethyl(hydrido)platinum(IV) chemistry related to methane activation: the effect of a tetradentate ligand

  摘要：

  The complex [PtMe2(TPMA)] (1), TPMA = tris(2-pyridylmethyl)amine, contains bidentate TPMA with two free pyridyl groups. It reacts with HX (X = CF3CO2, CF3SO3, BF4) at room temperature to yield [PtHMe2(TPMA)][X], which exists as an equilibrium mixture of two isomeric forms, each containing fac-tridentate TPMA. The major product has the hydride trans to a pyridyl group, but an equilibrium exists with the isomer in which the hydride is trans to amine. These cationic methyl(hydrido)platinum(IV) complexes are stable at room temperature for several hours, but undergo slow reductive elimination of CH4 to yield [PtMe(TPMA)][X], in which TPMA is mer-tridentate. The reaction of 1 with CF3SO3D in CD3OD gives only CH3D with no deuterium incorporation into the remaining methylplatinum group, and with MeI it yields [PtMe3(TPMA)][1]. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00148-8