[RuCl2((Z)-CH=CH(C6H4Me))(PPh3)2(NO)] | 1187974-35-1

• 英文名称: [RuCl2((Z)-CH=CH(C6H4Me))(PPh3)2(NO)]
• CAS: 1187974-35-1
• 化学式: C₄₅H₃₉Cl₂NOP₂Ru
• 分子量: 843.734
• InChiKey: QZBGNUFZOPWWPN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 [RuCl(=C=CH(C6H4Me))(PPh3)2(NO)] 以 二氯甲烷 为溶剂， 以91%的产率得到[RuCl2((Z)-CH=CH(C6H4Me))(PPh3)2(NO)]
  参考文献：
  名称：

  Protonation of a Ruthenium Vinylidene Complex with a NO Ligand Leading to Ruthenium Vinyl Complexes

  摘要：

  Treatment of a ruthenium, vinylidene complex bearing a bent-type NO ligand, RuCl(NO)(PPh(3))(2){=C=CH-(C(6)H(4)Me)} (1), with protic acids gave rise to the ruthenium vinyl complexes RuCl(X){(Z)-CH=CH(C(6)H(4)Me)}(PPh(3))(2)-(NO) (X = Cl (2a), O(2)CCF(3) (2b), FBF(3) (2c)) with concomitant transformation to linear-type NO. This indicates unusal protonation at the vinylidene alpha-carbon and anion-part coordination of the protic acids to the ruthenium atom (it the trans position to the resulting vinyl group. The coordinated BF(4) moiety of 2c was easily replaced to be a counteranion by MeCN solvent molecules, Yielding [RuCl{(Z)-CH=CH(C(6)H(4)Me)}(NCMe)(PPh(3))(2)(NO)]BP(4) (3).

  DOI：

  10.1021/om900576h