Zn(3,5-dimethylpyridine)2Br2 | 29173-00-0

• 英文名称: Zn(3,5-dimethylpyridine)2Br2
• 英文别名: Zn(3,5-lutidine)2Br2
• CAS: 29173-00-0
• 化学式: C₁₄H₁₈Br₂N₂Zn
• 分子量: 439.508
• InChiKey: PHFORVDDCMFAJG-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  zinc(II) bromide dihydrate 、 3,5-二甲基吡啶 以 乙醇 为溶剂， 生成 Zn(3,5-dimethylpyridine)2Br2
  参考文献：
  名称：

  Synthesis and Vibrational Spectra of Metal Halide Complexes of 3,5-Lutidine in Relation to their Structures

  摘要：

  The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L)(2)X-2, M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3.5-lutidine. Vibrational assignments are given for all the observed bands. Some structure-spectra correlations were found. For a given series of isomorphous complexes the sum of the difference of the values of the vibrational modes of 3,5-lutidine between the free ligand as liquid and the complexed ligand was found to increase in the order of the second ionization potentials of the metals. The frequency shifts were also found to depend on the halogen.

  DOI：

  10.1080/00945719708000260